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Crystal structure of K0.75[FeII 3.75FeIII 1.25(HPO3)6]- 0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions
(International Union of Crystallography, 2016)
Single crystals of the title compound, potassium hexaphosphitopentaferrate(
II,III) hemihydrate, K0.75[FeII
3.75FeIII
1.25(HPO3)6] 0.5H2O, were grown
under mild hydrothermal conditions. The crystal structure is isotypic ...