dc.contributor.author | Fidalgo Marijuan, Arkaitz | |
dc.contributor.author | Barandika Argoitia, Miren Gotzone | |
dc.contributor.author | Bazán Blau, Begoña del Pilar | |
dc.contributor.author | Urtiaga Greaves, Miren Karmele | |
dc.contributor.author | Arriortua Marcaida, María Isabel | |
dc.date.accessioned | 2016-03-16T17:10:13Z | |
dc.date.available | 2016-03-16T17:10:13Z | |
dc.date.issued | 2013-03-16 | |
dc.identifier.citation | CrystEngComm 20(15) : 4181-4188 (2013) | es |
dc.identifier.uri | http://hdl.handle.net/10810/17644 | |
dc.description | Artículo CrystEngComm 2013 | es |
dc.description.abstract | Two new CoP–bipy compounds have been synthesised and characterised, where P is TPP for compound 1 (TPP = meso-tetraphenylporphyrin) and TPPS for compound 2 (TPPS = meso-tetraphenylporphinetetrasulfonic
acid tetrasodium salt), and bipy is 4,49-bipyridine. Compound 1 consists of 1D polymers packed in a network where isolated porphyrin units are immobilized by an extended p-bond system. On the other hand, as we are aware, compound 2 is the first Co–TPPS compound in literature. It also consists of 1D polymers that are formed by the alternation of two distinct metal centres. These unprecedented polymers are packed forming cavities where crystallization molecules of water are located. The robustness of the hydrogen bond system and a topology based on nterpenetrated nets are responsible for the high thermal stability of compound 2. Additionally, a crystallochemical study confirmed the existence of a correlation between the degree of ruffled distortion of the porphyrin macrocycle and some selected
dihedral angles and distances for CoII porphyrins in literature. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovacion: (MAT2010-15375), Gobierno
Vasco: (Basque University System Research Groups, IT-630-13) | es |
dc.language.iso | eng | es |
dc.publisher | RSC Publishing | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.subject | metalloporphyrin | es |
dc.subject | MOF | es |
dc.subject | crystallochemical analysis | es |
dc.title | Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | © The Royal Society of Chemistry 2013 | |
dc.relation.publisherversion | http://pubs.rsc.org/en/content/articlelanding/2013/ce/c3ce40161h#!divAbstract | es |
dc.identifier.doi | 10.1039/c3ce40161h | |
dc.departamentoes | Grupo de investigación IMaCris / MaKrisI | es_ES |
dc.departamentoeu | IMaCris / MaKrisI ikerketa taldea | es_ES |