Show simple item record

dc.contributor.authorFidalgo Marijuan, Arkaitz
dc.contributor.authorBarandika Argoitia, Miren Gotzone
dc.contributor.authorBazán Blau, Begoña del Pilar
dc.contributor.authorUrtiaga Greaves, Miren Karmele
dc.contributor.authorArriortua Marcaida, María Isabel
dc.date.accessioned2016-03-16T17:21:42Z
dc.date.available2016-03-16T17:21:42Z
dc.date.issued2011-08-16
dc.identifier.citationPolyhedron 30(16) : 2711-2716 (2011)es
dc.identifier.urihttp://hdl.handle.net/10810/17650
dc.descriptionArtículo Polyhedron 2011es
dc.description.abstractSynthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is meso-tetra-(4-carboxyphenyl)porphyrin) coordination compound has been synthesized and structurally characterized. The compound is 2D via coordination bonds, and it exhibits strong hydrogen bonds that connect the planar arrays forming the 3D framework. The oxidation of the original FeII ions to FeIII accounts for the formation of this array, in which the topological analysis reveals a very high connectivity based on a simple extension fashion of the structure. DFT calculations have been also carried out to study the stabilization of the FeIII-compound. This is the third example of a 2D coordination compound based on TCPP in which the dimensionality refers just to coordination bonds, and no other ligands are present in the structure.es
dc.description.sponsorshipMinisterio de Ciencia e Innovación:(MAT2010-15375), Gobierno Vasco: (Basque University System Research Groups, IT-177-07)es
dc.language.isoenges
dc.publisherElsevieres
dc.relationinfo:eu-repo/grantAgreement/MICINN/MAT2010-15375
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectsupramolecular chemistryes
dc.subjectchiralityes
dc.subjectDFT calculationses
dc.subjectoxidationes
dc.titleSelf-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymeres
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holderAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S0277538711004906es
dc.identifier.doi10.1016/j.poly.2011.08.008
dc.departamentoesGrupo de investigación IMaCris / MaKrisIes_ES
dc.departamentoeuIMaCris / MaKrisI ikerketa taldeaes_ES


Files in this item

Thumbnail
Thumbnail
Thumbnail
Thumbnail

This item appears in the following Collection(s)

Show simple item record

Attribution-NonCommercial-NoDerivatives 4.0 International
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 International