Artículos
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Site-Selective Cu-Catalyzed Alkylation of α-Amino Acids and Peptides toward the Assembly of Quaternary Centers
(Wiley, 2018-10-15)The Cu(I)-catalyzed selective a-alkylation of a-amino acid and peptide derivatives with 2-alkyl-1,3-dioxolanes is reported. This oxidative coupling is distinguished by its site-specificity, high diastereoselectivity, and ... -
Molecular and biochemical analysis of XDH from Phaseolus vulgaris suggest that uric acid protects the enzyme against the inhibitory effects of nitric oxide in nodules
(Elsevier, 2019-09-05)Xanthine dehydrogenase (XDH) is essential for the assimilation of symbiotically fixed nitrogen in ureidic legumes. Uric acid, produced in the reaction catalyzed by XDH, is the precursor of the ureides, allantoin and ... -
Association of lifestyle factors and inflammation with sarcopenic obesity: data from the PREDIMED-Plus trial
(Wiley, 2019-05-29)Background Sarcopenia is a progressive age-related skeletal muscle disorder associated with increased likelihood of adverse outcomes. Muscle wasting is often accompanied by an increase in body fat, leading to 'sarcopenic ... -
Energetic cost of quantum control protocols
(IOP, 2019-10-28)We quantitatively assess the energetic cost of several well-known control protocols that achieve a finite time adiabatic dynamics, namely counterdiabatic and local counterdiabatic driving, optimal control, and inverse ...