Hydrogenolysis of dimethyl adipate over modified CuZnAl catalysts
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Date
2019-07-26Author
Garcia Fernandez, Jon Ander
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The purpose of this project is to perform stability tests of CuZnAl-based catalyst as a
substitute to the copper-chromium Adkins catalyst used for ester hydrogenolysis reactions.
This comes from the fact that chromium is a heavy and toxic metal and European Union have
passed legislation to limit its industrial use. For this reason, this project has been framed
inside green chemistry. CuZnAl was previously study as a substitute, but there is not enough
data about the stability of the catalyst over long reaction periods of time that would be
needed for industrial use. In this case, dimethyl adipate as a reactant was chosen and then
hexane-1,6-diol as a product was detected.