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Naphthyl-Containing Organophosphonate Derivatives of Keggin-Type Polyoxotungstates
(MDPI, 2016-06)
New organophosphonate derivatives of monovacant Keggin-type polyoxotungstates that contain naphthyl groups have been synthesized and characterized in both solid state and solution. Single-crystal structural analysis shows ...
A Robust Framework Based on Polymeric Octamolybdate Anions and Copper(II) Complexes of Tetradentate N-donor Ligands
(MDPI, 2018-01-06)
A new organic-inorganic compound based on octamolybdate building blocks and copper(II) complexes of tetradentate N-donor ligands has been hydrothermally synthesized, namely [Cu(cyclam)](2)[Mo8O26]center dot 1.5H(2)O (1), ...
Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))
(2016-02-16)
[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ...
Nuevos vanadatos híbridos de metales de transición. Síntesis hidrotermal, estudio estructural y de sus propiedades espectroscópicas y magnéticas
(Servicio Editorial de la Universidad del País Vasco/Euskal Herriko Unibertsitateko Argitalpen Zerbitzua, 2009-05-11)
En la búsqueda de nuevos materiales con posibles aplicaciones tecnológicas, los compuestos derivados de los óxidos de vanadio se presentan como una opción idónea, dada la gran versatilidad estructural de este tipo de ...
Estudio de series temporales y composición química del material particulado atmosférico en distintas áreas del País Vasco
(Servicio Editorial de la Universidad del País Vasco/Euskal Herriko Unibertsitatearen Argitalpen Zerbitzua, 2014-05-06)
Se presentan los resultados de los estudios realizados con el objetivo de contribuir a un mayor conocimiento de la contaminación atmosférica por material particualdo (PM, particulate matter), concretamente en la granulometría ...
Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material
(MDPI, 2016-01-15)
The processing of an originally non- porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal- organic porous materials, conceptually different to ...
Slot-Die Process of a Sol–Gel Photocatalytic Porous Coating for Large-Area Fabrication of Functional Architectural Glass
(MDPI, 2021-06-06)
The slot-die process is an appealing technology for the fabrication of coatings on large-area substrates. However, its application on the production of photocatalytic coatings based on sol–gel formulations remains virtually ...
Magnetic and Photoluminescent Sensors Based on Metal-Organic Frameworks Built up from 2-aminoisonicotinate
(2020-06-01)
In this work, three isostructural metal-organic frameworks based on first row transition metal ions and 2-aminoisonicotinate (2ain) ligands, namely, {[M(mu-2ain)2]·DMF}n [MII=Co (1), Ni (2), Zn (3)], are evaluated for their ...
On the Road to Sustainable Energy Storage Technologies: Synthesis of Anodes for Na-Ion Batteries from Biowaste
(MDPI, 2022-03-22)
Hard carbon is one of the most promising anode materials for sodium-ion batteries. In this work, new types of biomass-derived hard carbons were obtained through pyrolysis of different kinds of agro-industrial biowaste ...
Single-Ion Magnet and Photoluminescence Properties of Lanthanide(III) Coordination Polymers Based on Pyrimidine-4,6-Dicarboxylate
(MDPI, 2021-01-04)
Herein, we report the magnetic and photoluminescence characterization of coordination polymers (CP) built from the combination of lanthanide(III) ions, pyrimidine-4,6-dicarboxylate (pmdc) ligand and a co-ligand with formula ...