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Coordination compounds of organosulfur ligands as precursors of nanostructured materials.
(2017-07-18)
This work presents the synthesis and characterization of a series of coordination compounds based on metal(II)-organosulfur complexes as precursors of zero- and three-dimensional nanomaterials.On the one hand, thiocarboxylato ...
Synthesis and characterization of metal-organic framework aerogels
(2015)
[EN] Aerogels have become a material of interest to many scientists in the recent decades due to its unique physical properties which give it the potential to improve technologies in a variety of fields. MOF-based aerogel ...
Métodos no convencionales para la preparación de polímeros de coordinación porosos. Una aproximación económica, medioambientalmente amigable y escalable
(2015-07-16)
En la última década, se ha puesto de relieve una nueva clase de material cristalino poroso con esqueleto híbrido, formado por la unión de iones o clústeres metálicos a través de ligandos puentes, los MOFs (Metal-Organic ...
Exploring Reaction Conditions to Improve the Magnetic Response of Cobalt-Doped Ferrite Nanoparticles
(MDPI, 2018-01-25)
With the aim of studying the influence of synthesis parameters in structural and magnetic properties of cobalt-doped magnetite nanoparticles, Fe3-xCoxO4 (0 < x < 0.15) samples were synthetized by thermal decomposition ...
Immobilization of Polyoxometalates on Tailored Polymeric Surfaces
(MDPI, 2018-03)
Herein we describe the preparation of hybrid polymer-inorganic interfaces by the immobilization of polyoxometalate nanoclusters on functionalized polymer surfaces. The polymeric surfaces were made of polystyrene-b-poly(acrylic ...
Poly(l-lactide)-Based Anti-Inflammatory Responsive Surfaces for Surgical Implants
(MDPI, 2020-12-24)
In the last few decades, surgical implants have been widely used to restore the function of damaged bones or joints. However, it is essential to receive antibiotic or anti-inflammatory treatment to circumvent significant ...
SupraMOFs: Supramolecular porous materials assembled from metal-nucleobase discrete entities
(2015-07-13)
El objeto de este trabajo se centra en la síntesis y caracterización de nuevos materiales cristalinos con huecos potencialmente accesibles a las moléculas de adsorbato. Esta meta se ha alcanzado mediante el uso de compuestos ...
Toward Advanced Functional Systems: Honeycomb-Like Polymeric Surfaces Incorporating Polyoxovanadates with Surface-Appended Copper-Cyclam Complexes
(MDPI, 2019-06-22)
In this work the immobilization of hybrid polyoxometalates (POMs) onto functional polymeric surfaces is exposed and discussed. Thus, various hybrid polymerinorganic films were prepared by anchoring selected hybrid POMs ...
A Charge-Transfer Salt Based on Ferrocene/Ferrocenium Pairs and Keggin-Type Polyoxometalates
(MDPI, 2018-11-30)
A new hybrid inorganic-organometallic salt has been obtained from the reaction of the Keggin-type silicotungstate anion with ferrocene in a water/methanol mixture as a result of the partial oxidation of ferrocene molecules ...
Single-Crystal to Single-Crystal Reversible Transformations Induced by Thermal Dehydration in Keggin-Type Polyoxometalates Decorated with Copper(II)-Picolinate Complexes: The Structure Directing Role of Guanidinium
(MDPI, 2015-05-27)
Three new hybrid inorganic-metalorganic compounds containing Keggin-type polyoxometalates, neutral copper(II)-picolinate complexes and guanidinium cations have been synthesized in bench conditions and characterized by ...