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Influence of the Ambient Storage of LiNi0.8Mn0.1Co0.1O2 Powder and Electrodes on the Electrochemical Performance in Li-ion Technology
(MDPI, 2022-07-28)
Nickel-rich LiNi0.8Mn0.1Co0.1O2 (NMC811) is one of the most promising Li-ion battery cathode materials and has attracted the interest of the automotive industry. Nevertheless, storage conditions can affect its properties ...
Development of Fe3-xMxO4 (M = Co and Ga) nanomaterials for biomedical applications
(2022-04-01)
El presente trabajo se ha centrado en el desarrollo de nanomateriales para su posible uso en aplicaciones biomédicas. La optimización del método de descomposición térmica de precursores metálicos, ha sido posible obtener ...
Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework
(American Chemical Society, 2021-09-21)
[EN]The hybrid compound [Cu(cyclam)(H2O)(2)](0.5)[{Cu(cyclam)}(1.5){B-H2As2Mo6O26(H2O)}].9H(2)O (1) (cyclam = 1,4,8,11- tetraazacyclotetradecane) was synthesized in aqueous solution by reacting the {Cu(cyclam)}(2+) complex ...
Reversible First-Order Single Crystal to Single Crystal Thermal Phase Transition in [(CH3)3CNH3]4[V4O12]
(MDPI, 2022-08-17)
[EN] The well-known compound tetrakis(tert-butylammonium)-cyclo-tetrametavanadate (V), [(CH3)3CNH3]4[V4O12] (1h_RT), which crystallizes in the tetragonal I4/m space group, undergoes an irreversible solid state transformation ...
Direct Arylation in the Presence of Palladium Pincer Complexes
(MDPI, 2021-07-20)
Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer ...
Transannular Enantioselective (3 + 2) Cycloaddition of Cycloalkenone Hydrazones under Bronsted Acid Catalysis.
(American Chemical Society, 2021-11-19)
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) cycloaddition catalyzed by a chiral phosphoric acid. The reaction provides high yields and excellent stereocontrol in the ...
Porous TiO2 thin film-based photocatalytic windows for an enhanced operation of optofluidic microreactors in CO2 conversion
(Elsevier, 2021-06-25)
[EN] Using a photocatalytic window can simplify the design of an optofluidic microreactor, providing also a more straightforward operation. Therefore, the development of TiO2coatings on glass substrates seems appealing, ...
Ferromagnetic supramolecular metal-organic frameworks for active capture and magnetic sensing of emerging drug pollutants
(Elsevier ; Cell Press, 2021-05-19)
[EN] Capture and sensing of emerging pollutants is one of the increasing environmental concerns due to the adverse ecological and human health effects. Here, we report the synthesis of a supramolecular metal-organic framework ...
Palladium-Catalyzed Domino Cycloisomerization/Double Condensation of Acetylenic Acids with Dinucleophiles
(MDPI, 2022-01-17)
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Open AccessArticle
Palladium-Catalyzed Domino Cycloisomerization/Double Condensation of Acetylenic Acids with Dinucleophiles
by Nerea Conde
, María Teresa Herrero
, Garazi Urgoitia
and Raul ...
Prioritization based on risk assessment to study the bioconcentration and biotransformation of pharmaceuticals in glass eels (Anguilla anguilla) from the Adour estuary (Basque Country, France)
(Elsevier, 2022-10)
The presence of contaminants of emerging concern in the aquatic environment directly impacts water-living organisms and can alter their living functions. These compounds are often metabolized and excreted, but they can ...