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Now showing items 21-25 of 25
Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
(RSC Publishing, 2013-03-16)
Two new CoP–bipy compounds have been synthesised and characterised, where P is TPP for compound 1 (TPP = meso-tetraphenylporphyrin) and TPPS for compound 2 (TPPS = meso-tetraphenylporphinetetrasulfonic
acid tetrasodium ...
Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer
(Elsevier, 2011-08-16)
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)
Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ...
Synthesis of new Ln4(Al2O6F2)O2 (Ln = Sm,Eu,Gd) phases with a cuspidine-related structure
(International Union of Crystallography, 2019-01)
The first fluorination of the cuspidine-related phases of Ln4(Al2O7□)O2 (where Ln = Sm, Eu, Gd) is reported. A low-temperature reaction with poly(vinylidene difluoride) lead to the fluorine being substituted in place of ...