Listar Grupo de investigación IMaCris / MaKrisI por título
Mostrando ítems 6-25 de 62
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Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
(Elsevier, 2017-03)Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ... -
Celdas de pilas de oxidó solido, avance en el procesado de materiales
(2016-06-24)Este trabajo está enfocado a la síntesis y al procesado de los componentes de las pilas de combustible de óxido sólido (SOFC). La configuración empleada consiste en celdas (ánodo/electrolito/cátodo) soportadas por el ... -
Characterization of cobalt based TPP-bipy coordination polymer
(2016-04-22)Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ... -
Characterization of Ln4Al2O9 (Ln=Y, Sm, Eu, Gd, Tb) rare-earth aluminates as new high-temperature barriers
(Elsevier, 2018-06-01)A family of cuspidine-type rare-earth (RE) aluminates with the general formula Ln4Al2O9 (Ln= Y, Sm, Eu, Gd, Tb) was prepared for potential use as thermal-barrier coating (TBC) materials with appropriate properties. Various ... -
Combustion synthesis and characterization of Ln1−xMxCr0.9Ni0.1O3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) perovskites for SOFCs anodes
(Elsevier, 2018-02-01)A series of chromite perovskites with the general formula Ln1−xMxCr0.9Ni0.1O3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) has been prepared by three combustion synthesis routes using a different combustible substance ... -
Composite beta-AgVO3@V5+1.6V4+0.4O4.8 hydrogels and xerogels for catalytic applications
(2016-04-07)Silver vanadium oxides and vanadium oxides, and concretely β-AgVO3 phase, have received considerable attention in the last decade due to their unique physical and chemical properties, including electrochemical and ... -
Conductividad superprotónica en MOFs metaloporfirínicos bioinspirados
(2017-07-09)Los materiales de tipo MOF muestran un gran potencial para una amplia gama de aplicaciones debido a su elevada porosidad, baja densidad y facilidad en la modificación estructural. En particular, los MOF basados en ... -
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI, 2015-04-15)Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ... -
Crystal structure and characterization of a new μ-oxo bridged iron porphyrin
(2016-04-22)Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ... -
Crystal structure of K0.75[FeII 3.75FeIII 1.25(HPO3)6]- 0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions
(International Union of Crystallography, 2016)Single crystals of the title compound, potassium hexaphosphitopentaferrate( II,III) hemihydrate, K0.75[FeII 3.75FeIII 1.25(HPO3)6] 0.5H2O, were grown under mild hydrothermal conditions. The crystal structure is isotypic ... -
CuII-based metal-organic nanoballs for very rapid adsorption of dyes and iodine
(The Royal Society of Chemistry, 2016-02-03)CuII nanoballs have been determined to be among the best MOPs (Metal–Organic Polyhedra) reported so far for the adsorption of small molecules, with the highlighting advantage of rapid kinetics, which focuses on their ... -
Dehydration for a solid coordination network based on CuII-(py)2C(OH)2 trimers
(2016-04-22)Materials consisting of metal ions or clusters that are linked by polyfunctional organic ligands form networks of different dimensionalities. Their structural features, including large cavities and high surface areas, ... -
Designing multifunctional pigments for an improved energy efficiency in buildings
(Elsevier, 2017-07-15)Materials science offers solutions that when are combined can offer important energy savings in the building sector. In this study, high reflectance coating and thermal storage capacity are combined with the aim of improving ... -
Effect of the A cation size disorder and synthesis conditions on the properties of an iron perovskite series
(2015-11-18)Solid state chemistry thrives on a rich variety of solids that can be synthesized using a wide range of techniques. It is well known that the preparative route plays a critical role on the physical and chemical properties ... -
Effect of the synthesis conditions on the properties of La0.15Sm0.35Sr0.08Ba0.42FeO3-a cathode material for SOFCs
(2017-09-13)The perovskite La0.15Sm0.35Sr0.08Ba0.42FeO3-a has been prepared by the glycine nitrate (GNC) route, varying the fuel/oxidizer ratio (glycine/nitrate, G/N= 1 and 2) and cooling rate (slow cooling and air-quenched), in order ... -
Effects of synthetic conditions on the structural, stability and ion conducting properties of Li0.30(La0.50Ln0.50)0.567TiO3 (Ln= La, Pr, Nd) solid electrolytes for rechargeable lithium batteries
(Elsevier Ltd and Techna Group S.r., 2014-02-03)The structure, thermal stability, morphology and ion conductivity of titanium perovskites with the general formula Li3xLn2/3−xTiO3 (Ln = rare earth element; 3x= 0.30) are studied in the context of their possible use as ... -
Electrochemical and degradation behaviour study of different SOFC compounds
(2017-04-07)The present work is focused on manufacturing processes of the solid oxide fuel cell (SOFC) components with previously self-synthesized materials by combustion method [1-2]. The configuration used consists of planar ele ... -
Encapsulation of β-alanine model amino-acid in zirconium(IV) metal organic frameworks: Defect engineering to improve host guest interactions
(Elsevier, 2020-04)Metal-Organic Frameworks (MOFs) are porous coordination networks assembled through metal complexes with organic linkers. Due to their chemical versatility, these materials are being investigated for various applications ... -
Fe−TPP Coordination Network with Metalloporphyrinic Neutral Radicals and Face-to-Face and Edge-to-Face π−π Stacking
(ACS Publications, 2013-06-25)Compound ([FeTPPbipy]•)n (TPP = meso-tetraphenylporphyrin and bipy = 4,4′-bipyridine) is the first example of a Fe−TPP−bipy coordination network, and it consists of 1D polymers packed through face-to-face and edge-to-face ... -
Functionalization of Cu3BTC2@IL composites with Pd(II) for catalytic applications
(2017-10-29)Metal-organic frameworks could be excellent supports for active catalytic species in order to obtain heterogeneous and reusable catalysts, easily removable from the reaction media.[1,2] Additionally, the presence of ...