dc.contributor.author | Fernández, Belén | |
dc.contributor.author | Oyarzabal Epelde, Itziar | |
dc.contributor.author | Seco Botana, José Manuel | |
dc.contributor.author | San Sebastián Larzabal, Eider | |
dc.contributor.author | Fairen-Jiménez, David | |
dc.contributor.author | Gómez-Ruiz, Santiago | |
dc.contributor.author | Salinas-Castillo, Alfonso | |
dc.contributor.author | Calahorro, Antonio J. | |
dc.contributor.author | Rodríguez-Diéguez, Antonio | |
dc.date.accessioned | 2016-05-12T13:30:46Z | |
dc.date.available | 2016-05-12T13:30:46Z | |
dc.date.issued | 2016-02 | |
dc.identifier.citation | Polymers 8(2) : (2016) // Article ID 39 | es |
dc.identifier.issn | 2073-4360 | |
dc.identifier.uri | http://hdl.handle.net/10810/18241 | |
dc.description.abstract | We report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4-dicarboxylic acid (H(2)abd) as ligand, synthesized by soft hydrothermal routes. Both materials show isostructural three-dimensional networks with channels along a axis and display intense photoluminescence properties in the solid state at room temperature. Textural properties of the metal-organic frameworks (MOFs) have been fully characterized although no appreciable porosity was obtained. Magnetic properties of these materials were studied, highlighting the dysprosium material displays slightly frequency-dependent out of phase signals when measured under zero external field and under an applied field of 1000 Oe. | es |
dc.description.sponsorship | This work was supported by the MEC of Spain (Project CTQ2011-24478) and the Junta de Andalucia (FQM-1484 and FQM-195). David Fairen-Jimenez thanks the Royal Society for a University Research Fellowship. Itziar Oyarzabal is grateful to the Departamento de Educacion, Universidades e Investigacion del Gobierno Vasco for a predoctoral fellowship. The authors thank for technical and human support provided by SG Iker Gipuzkoa of UPV/EHU. | es |
dc.language.iso | eng | es |
dc.publisher | MDPI | es |
dc.rights | info:eu-repo/semantics/openAccess | es |
dc.subject | metal-organic framework | es |
dc.subject | dysprosium | es |
dc.subject | terbium | es |
dc.subject | magnetism | es |
dc.subject | luminescence | es |
dc.subject | crystal-structures | es |
dc.subject | fluorescence | es |
dc.subject | complexes | es |
dc.subject | design | es |
dc.title | Luminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linker | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access
article distributed under the terms and conditions of the Creative Commons by Attribution
(CC-BY) license (http://creativecommons.org/licenses/by/4.0/). | es |
dc.relation.publisherversion | http://www.mdpi.com/2073-4360/8/2/39 | es |
dc.identifier.doi | 10.3390/polym8020039 | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |
dc.subject.categoria | CHEMISTRY, MATERIALS | |