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Ba+2 ion trapping using organic submonolayer for ultra-low background neutrinoless double beta detector
(Nature, 2022-12)
If neutrinos are their own antiparticles the otherwise-forbidden nuclear reaction known as neutrinoless double beta decay can occur. The very long lifetime expected for these exceptional events makes its detection a daunting ...
Metal-Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols
(American Chemical Society, 2022-11)
A new family of metal–organic frameworks (MOFs) named GR-MOFs with the chemical formula {[Mx(BCA)y](H2O)z(DMF)w} (x,y,z,w: 1,1,2,0; 1,1.5,0,1; 1,2,2,1; and 1,1,0,2 for GR-MOF-11 to 14, respectively) based on s-block [M: ...
Experimental and theoretical study of the effect of different functionalities of graphene oxide/polymer composites on selective CO2 capture
(Nature, 2022-01)
There is a constant need for versatile technologies to reduce the continuously increasing concentration of CO2 in the atmosphere, able to provide effective solutions under different conditions (temperature, pressure) and ...
Tailoring of Textural Properties of 3D Reduced Graphene Oxide Composite Monoliths by Using Highly Crosslinked Polymer Particles toward Improved CO2 Sorption
(American Chemical Society, 2022-12)
The main constraint on developing a full potential for CO2 adsorption of 3D composite monoliths made of reduced graphene oxide (rGO) and polymer materials is the lack of control of their textural properties, along with the ...
Structuring Cu/ZnO/Al2O3 catalyst for methanol synthesis: Slurry additive effect in the washcoating method
(Elsevier, 2022-12)
The best slurry formulation to prepare a structured catalyst for methanol synthesis reaction by washcoating method was investigated. The effect of different inorganic oxide colloids in the slurry preparation of Cu/ZnO/Al2O3 ...
Slow Magnetic Relaxation and Luminescent Properties of Mononuclear Lanthanide-Substituted Keggin-Type Polyoxotungstates with Compartmental Organic Ligands
(American Chemical Society, 2022-02-07)
The reaction of mid to late lanthanide ions with the N,N'-dimethyl-N,N'-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylene-diamine organic ligand and monolacunary Keggin type [alpha-SiW11O39]8- anion affords a series of ...
Easy Handling and Cost-Efficient Processing of a Tb3+-MOF: The Emissive Capacity of the Membrane-Immobilized Material, Water Vapour Adsorption and Proton Conductivity
(MDPI, 2022-12-08)
The development of convenient, non-complicated, and cost-efficient processing techniques for packing low-density MOF powders for industry implementation is essential nowadays. To increase MOFs’ availability in industrial ...
Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
(MDPI, 2022-11-13)
The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3( ...
Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand
(MDPI, 2022-11-21)
Due to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials ...
Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
(American Chemical Society, 2022-08)
Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ...