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A metal-organic framework based on Co(II) and 3-aminoisonicotinate showing specific and reversible colourimetric response to solvent exchange with variable magnet behaviour
(Elsevier, 2022-06)
[EN] A versatile metal-organic system consisting of Co-based compounds that show reversible transformations between a 3D metal-organic framework (MOF) of {[Co(mu-3isoani)(2)]center dot DMF}(n) (1) formula (where 3isoani - ...
A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls
(MDPI, 2022-03-06)
Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n ...
Formation of Irida-β-ketoimines and PCNamine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H3N–BH3
(ACS, 2022-12-01)
Aliphatic diamines [(H2N(CH2)nNHR) (a–d) n = 2: R = H (a), R = CH3 (b), R = C2H5 (c), n = 3, R = H (d) or rac-2-(aminomethyl)piperidine (e)] react with [IrH(Cl){(PPh2(o-C6H4CO))2H}] in THF to afford ketoimine complexes ...
Combined experimental and theoretical investigation on the magnetic properties derived from the coordination of 6-methyl-2- oxonicotinate to 3d-metal ions
(Royal Society of Chemistry, 2022-06-08)
Five new compounds are reported herein starting from 2-hydroxy-6-methylnicotinic acid (H2h6mnic)
and first-row transition metal ions, although H2h6mnic shows a prototropy in solution to lead to the
6-methyl-2-oxonicotinate ...
Magneto-thermal properties and slow magnetic relaxation in Mn(II)Ln(III) complexes: Influence of magnetic coupling on the magneto-caloric effect
(2022-08-05)
A family of Mn(II)Ln(III) dinuclear and tetranuclear complexes (Ln = Gd and Dy) has been prepared from the
compartmental ligands N,N’-dimethyl-N,N’-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylenediamine
(H2L1
) and ...
Fast successive self-nucleation and annealing (SSA) thermal fractionation protocol for the characterization of polyolefin blends from mechanical recycling
(Wiley, 2022-04-29)
The sorting stage of mechanical recycling of post-consumer polyolefins has severe challenges. Polypropylene (PP) is often contaminated with polyethylene (PE) and vice versa. To meet quality requirements, characterization ...
Evolution of main polyphenolics during cidermaking
(Elsevier, 2022-09)
This work reports the evolution of polyphenolic compounds content during the cidermaking process in the Basque Country (Northern Spain). Fourteen monovarietal musts were obtained throughout three seasons (13 different, one ...