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Structure of a dinickel(II)-dithiolate bridged macrocyclic complex synthesised via a novel solvent-assisted disulfide cleavage reaction
(Elsevier, 2023-01)
The reaction of 2,6-diformyl-4-methylphenyl disulfide with [Ni(tn)3]Cl2 (tn = 1,3-diaminopropane), in methanol and in the presence of NaBPh4 resulted in the isolation of [Ni2(L1)](DMF)2(BPh4)2 (I), (L1 = 15,95-dimethyl-3 ...
Single-Ion Magnet and Photoluminescence Properties of Lanthanide(III) Coordination Polymers Based on Pyrimidine-4,6-Dicarboxylate
(MDPI, 2021-01-04)
Herein, we report the magnetic and photoluminescence characterization of coordination polymers (CP) built from the combination of lanthanide(III) ions, pyrimidine-4,6-dicarboxylate (pmdc) ligand and a co-ligand with formula ...
Design and Test of a Miniature Hydrogen Production Integrated Reactor
(MDPI, 2021-04-16)
A detailed study of the experimental issues involved in the design and operation of a methanol steam microreformer is presented in this paper. Micromachining technology was utilized to fabricate a metallic microchannel ...
Towards improved performance of waterborne polymer dispersions through creation of dense ionic interparticle network within their films
(Elsevier, 2023-01)
To overcome the main challenge of low performance of the waterborne polymer coatings due to the particulate nature of the polymer dispersions and the complex film formation process, in this work we implemented the strategy ...
Crosslinking versus interdiffusion in two pot one pack acetoacetoxy-amine based binder system
(Elsevier, 2023-01)
A two-pot-one-pack waterborne crosslinking system is studied by following the crosslinking and interdiffusion between the polymer particles functionalized with acetoacetoxy on one hand and with polyethyleneimine on the ...
A Versatile Chemoenzymatic Nanoreactor that Mimics NAD(P)H Oxidase for the In Situ Regeneration of Cofactors
(Wiley, 2022-09)
Herein, we report a multifunctional chemoenzymatic nanoreactor (NanoNOx) for the glucose-controlled regeneration of natural and artificial nicotinamide cofactors. NanoNOx are built of glucose oxidase-polymer hybrids that ...
Ba+2 ion trapping using organic submonolayer for ultra-low background neutrinoless double beta detector
(Nature, 2022-12)
If neutrinos are their own antiparticles the otherwise-forbidden nuclear reaction known as neutrinoless double beta decay can occur. The very long lifetime expected for these exceptional events makes its detection a daunting ...
From Lab to Manufacturing Line: Guidelines for the Development and Upscaling of Aqueous Processed NMC622 Electrodes
(The Electrochemical Society, 2023-01-24)
Lithium-ion batteries (LIBs) have facilitated the transition to a more sustainable energy model. Paradoxically, current high energy cathodes are industrially processed using organic solvents, which are deleterious for the ...
Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand
(Royal Society of Chemistry, 2023)
The synthesis and iridium coordination chemistry of a new pyridine-based phosphinito pincer ligand 2,6-
(ArF2PO)2 C5H 3N (PONOP-ArF ; ArF = 2-(CF3)C 6 H4 ) are described, where the P-donors have ortho-
trifluoromethylphenyl ...
Metal-Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols
(American Chemical Society, 2022-11)
A new family of metal–organic frameworks (MOFs) named GR-MOFs with the chemical formula {[Mx(BCA)y](H2O)z(DMF)w} (x,y,z,w: 1,1,2,0; 1,1.5,0,1; 1,2,2,1; and 1,1,0,2 for GR-MOF-11 to 14, respectively) based on s-block [M: ...