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Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
(MDPI, 2022-11-13)
The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3( ...
Modulation of Pore Shape and Adsorption Selectivity by Ligand Functionalization in a Series of “rob”-like Flexible Metal-Organic Frameworks
(RSC, 2018-08-08)
We report the synthesis of a new family of four new isoreticular metal–organic frameworks (MOFs) based on
Cu–Cu paddle-wheel building units. The four MOFs contain 1D microchannels modulated by chemical
functionalisation ...
Antioxidant activities and selenogene transcription in the european sea bass (Dicentrarchus labrax) liver depend, in a non-linear manner, on the Se/Hg molar tatio of the feeds
(Springer Nature ; Humana Press, 2021-07-01)
[EN] Feeding 3.9 and 6.7 mg Hg/kg (Se/Hg molar ratios of 0.8 and 0.4, respectively) for 14 days negatively affected Dicentrarchus
labrax growth and total DNTB- and thioredoxin-reductase (TrxR) activities and the transcription ...
Development of a Novel Method for the In-Situ Dechlorination of Immovable Iron Elements: Optimization of Cl- Extraction Yield Through Experimental Design
(Springer, 2021-05-24)
The conservation of iron objects exposed to marine aerosol is threatened by the formation of akaganeite, a highly unstable Cl-bearing corrosion phase. As akaganeite formation is responsible of the exfoliation of the rust ...
Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand
(MDPI, 2022-11-21)
Due to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials ...
Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear Co3 II Complex
(ACS, 2023-11-22)
A new linear trinuclear Co(II)3 complex with a formula of [{Co(μ-L)}2Co] has been prepared by self-assembly of Co(II) ions and the N3O3-tripodal Schiff base ligand H3L, which is obtained from the condensation of ...
Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
(Elsevier, 2021-05-07)
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the perspective of how information
can be stored. The current bit, occupying few hundreds of nanometers in present devices, would be
minimized ...
Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
(American Chemical Society, 2022-08)
Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ...
A metal-organic framework based on Co(II) and 3-aminoisonicotinate showing specific and reversible colourimetric response to solvent exchange with variable magnet behaviour
(Elsevier, 2022-06)
[EN] A versatile metal-organic system consisting of Co-based compounds that show reversible transformations between a 3D metal-organic framework (MOF) of {[Co(mu-3isoani)(2)]center dot DMF}(n) (1) formula (where 3isoani - ...
Synthesis, Structural Features and Physical Properties of a Family of Triply Bridged Dinuclear 3d-4f Complexes
(MDPI, 2021-02-05)
New dinuclear MII-LnIII complexes of general formulas [Cu(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN·H2O (LnIII = Gd (1), Tb (2), Dy (3) and Er (4)), [Ni(CH3CN)(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN (LnIII = Nd (5), Gd (6), Tb (7), Dy (8), Er (9) ...