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Deactivation of Ni spinel derived catalyst during the oxidative steam reforming of raw bio-oil
(Elsevier, 2020-05-12)
Deactivation of a bulk catalyst derived from NiAl2O4 spinel during the oxidative steam reforming (OSR) of raw bio-oil has been studied. The experiments were performed in a continuous system with two units in series: a ...
Deactivation kinetics for the conversion of dimethyl ether to olefins over a HZSM-5 zeolite catalyst
(2016-11-16)
A deactivation kinetic equation for the conversion of dimethyl ether (DME) to olefins (DTO process) has been established. The catalyst has been prepared with a HZSM-5 zeolite (SiO2/Al2O3 ratio of 280) agglomerated with ...
Co-cracking of high-density polyethylene (HDPE) and vacuum gasoil (VGO) under refinery conditions
(Elsevier B.V., 2020-02)
The co–cracking of a 5 wt% of high–density polyethylene (HDPE) dissolved in vacuum gasoil (VGO) under conditions similar to those of the industrial fluid catalytic cracking (FCC) unit has been studied. The main goal has ...
Effect of calcination/reduction conditions of Ni/La2O3–αAl2O3 catalyst on its activity and stability for hydrogen production by steam reforming of raw bio-oil/ethanol
(Elsevier, 2014-04-05)
The influence of calcination and reduction temperatures of Ni/La2O3–αAl2O3 catalyst used in the steam reforming of raw bio-oil was studied in the 550–850 °C range. The experiments were conducted by continuously feeding a ...
Kinetic modeling of CO2 + CO hydrogenation to DME over a CuO-ZnO-ZrO2@SAPO-11 core-shell catalyst
(Elsevier, 2020-09-01)
A kinetic model for the CO2 + CO hydrogenation to dimethyl ether (DME) in a single step over an original core-shell structured CuO-ZnO-ZrO2@SAPO-11 bifunctional catalyst (metallic in the core and acid in shell) has been ...
Reaction conditions effect and pathways in the oxidative steam reforming of raw bio-oil on a Rh/CeO2-ZrO2 catalyst in a fluidized bed reactor
(Elsevier, 2017-12-07)
A reaction scheme has been proposed for the oxidative steam reforming (OSR) of raw bio-oil on a Rh/CeO2-ZrO2 catalyst, based on the study of the effect reaction conditions (temperature, space time, oxygen/carbon ratio and ...
Regeneration of NiAl2O4 spinel type catalysts used in the reforming of raw bio-oil
(Elsevier, 2018-12-01)
The regenerability of Ni catalysts in reforming reactions is a key factor for process viability. Accordingly, this study addresses the regeneration of two spinel NiAl2O4 type catalysts by reaction-regeneration cycles in ...
Regenerability of a Ni catalyst in the in-line catalytic steam reforming of biomass pyrolysis volatiles
(Elsevier, 2018-12)
A study has been carried out of the regenerability of a commercial Ni catalyst used in the steam reforming of volatiles from biomass pyrolysis, determining the evolution of the reaction indices in successive reaction-regeneration ...
Role of operating conditions in the catalyst deactivation in the in-line steam reforming of volatiles from biomass fast pyrolysis
(Elsevier, 2017-12-09)
The effect of reforming conditions (temperature, space time and steam/biomass ratio (S/B)) has been studied in the continuous biomass pyrolysis and in-line catalytic steam reforming process in order to establish suitable ...
Taking advantage of the excess of thermal naphthas to enhance the quality of FCC unit products
(Elsevier B.V., 2020-09-26)
Today, many European refineries finish up with excess of low-quality thermal naphthas that are hard to be marketed and, commonly, end being absorbed by catalytic naphthas at the expense of their higher quality. In this ...