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Tailor-Made Synthesis of Hydrosilanols, Hydrosiloxanes, and Silanediols Catalyzed by di-Silyl Rhodium(III) and Iridium(III) Complexes
(ACS, 2023-02)
Siloxanes and silanols containing Si–H units are important building blocks for the synthesis of functionalized siloxane materials, and their synthesis is a current challenge. Herein, we report the selective synthesis of ...
Magneto-thermal properties and slow magnetic relaxation in Mn(II)Ln(III) complexes: Influence of magnetic coupling on the magneto-caloric effect
(2022-08-05)
A family of Mn(II)Ln(III) dinuclear and tetranuclear complexes (Ln = Gd and Dy) has been prepared from the
compartmental ligands N,N’-dimethyl-N,N’-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylenediamine
(H2L1
) and ...
Cryo-TEM assessment of droplet nucleation efficiency in hybrid acrylic/CeO2 semibatch miniemulsion polymerization
(ACS, 2014-11-26)
Monomer droplet nucleation has been successfully tracked in a seeded semibatch miniemulsion polymerization with miniemulsion feeding. Taking advantage of the marker capacity of CeO2 nanoparticles two polymerizations were ...
Lactide-caprolactone copolymers with tuneable barrier properties for packaging applications
(Elsevier, 2020-06-07)
Lactide-caprolactone copolymers have been synthetized employing two metallic catalysts, Ph3Bi and SnOct2. The analysis of the microstructure by NMR reveals that gradient like copolymers are obtained with SnOct2 catalyst, ...
Evaluation of SWAT models performance to simulate streamflow spatial origin. The case of a small forested watershed
(Elsevier, 2015-06-01)
The Soil and Water Assessment Tool (SWAT) model has been applied widely in many types of environment with different goals. The purpose of this paper is to assess the ability of SWAT to simulate hydrological processes in ...
Evidence of mercury sequestration by carbon nanotubes and nanominerals present in agricultural soils from a coal fired power plant exhaust
(Elsevier, 2019-10)
Mercury (Hg) in agricultural soils could have negative effects on the environment and the human health. The exposure to high level of Hg through different absorption pathways, such as ingestion and diet through soil-plant ...
UV tunable biobased pressure sensitive adhesives containing piperonyl methacrylate
(ACS, 2019)
Novel waterborne pressure sensitive adhesives (PSA) with biobased contents up to 71%, and UV-light tunable features have been developed using piperonyl methacrylate as hard monomer. The biobased monomer was synthesized ...
UV screening clear coats based on encapsulated CeO2 hybrid latexes
(RSC, 2012-12-21)
CeO2 nanoparticles have been successfully incorporated into acrylic latex particles with an excellent homogeneous distribution (mostly one inorganic particle per polymer particle) and limited aggregation (inorganic ...
Phosphonium-based ionic liquids: Economic and efficient catalysts for the solvent-free cycloaddition of CO2 to epoxidized soybean vegetable oil to obtain potential bio-based polymers precursors
(Elsevier, 2021-09-25)
A series of phosphonium-based ionic liquids have been prepared in one step in a simple way from inexpensive feedstocks. The prepared ionic liquids have been successfully tested as catalysts in the solvent-free cycloaddition ...
Photoswitchable catalysis using organometallic complexes
(Royal Society of Chemistry, 2020-04-30)
This review describes the state of the art in photoswitchable organometallic catalysis, underlining the importance of ligand design. The implementation of spatio-temporal control on known catalytic processes
has been ...