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Now showing items 3511-3520 of 4794
Immunoproteomics-Based Analysis of the Immunocompetent Serological Response to Lomentospora prolificans
(ACS, 2016-01-06)
The filamentous fungus Lomentospora prolificans is an emerging pathogen causing severe infections mainly among the immunocompromised population. These diseases course with high mortality rates due to great virulence of the ...
A Potassium Metal-Organic Framework based on Perylene- 3,4,9,10-tetracarboxylate as Sensing Layer for Humidity Actuators
(Nature Publishing, 2018-09-26)
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on the perylene-3,4,9,10-tetracarboxylate linker and potassium as metallic centre. We report the formation of this K-based MOF using ...
Palladium-catalysed Heck-type alkenylation reactions in the synthesis of quinolines. Mechanistic insights and recent applications
(Royal Society of Chemistry, 2020-05-18)
Quinoline and quinolone cores are present in a wide variety of pharmaceuticals, agrochemicals and materials, as well in ligands/catalysts in asymmetric synthesis. Transition-metal catalysed based approaches have played a ...
Selective Pd(II)-catalyzed Acylation of Pyrrole with Aldehydes. Application to the Synthesis of Celastramycin analogues and Tolmetin
(Wiley-VCH, 2020-04-27)
The Pd(II)-catalyzed C-2 acylation of pyrrole with aldehydes in the presence of TBHP as oxidant has been studied for the synthesis of di(hetero)aryl ketones. The use of 2-pyrimidine as directing group leads to 2-acylpyrroles ...
The Prayer to Pan of Plato’s Phaedrus (279b8–c3): An Exhortation to Exercise the Philosophical Virtue
(Taylor & Francis, 2019-04-04)
The current article offers a new reading of Socrates’ prayer to Pan in Plato’s Phaedrus. By means of a comprehensive approach, the paper shows that the prayer not only gathers together the most relevant topics dealt with ...
Designing Single-Molecule Magnets as Drugs with Dual Anti-Inflammatory and Anti-Diabetic Effects
(MDPI, 2020-04-28)
We have designed and synthesized two novel cobalt coordination compounds using bumetanide (bum) and indomethacin (ind) therapeutic agents. The anti-inflammatory effects of cobalt metal complexes with ind and bum were assayed ...
Si Dionisio lo dice, o no? Sancti Spiritus y el acto de toma de posesión del territorio
(Universidad Nacional de Rosario, 2020-11-28)
The proximity of the V centenary of the construction of the Sancti Spiritus settlement has made it necessary to reflect on the anniversary of the arrival of Sebastian Gaboto at the confluence of the Carcaraña ...
Marivaux contra la tiranía: la utopía igualitaria de Lîle des esclaves
(Universidad de Murcia, 2019-11-15)
Cet article propose une étude de “L’île des esclaves” de Pierre Carlet de Chamblain de Marivaux (1725). Ce romancier et dramaturge analysa dans ses œuvres les progrès de l’amour et la fragilité des sentiments ...
Luminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linker
(MDPI, 2016-02)
We report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4-dicarboxylic acid (H(2)abd) as ligand, synthesized by soft hydrothermal routes. Both materials ...
Carboxylates as Nucleophiles in the Enantioselective Ring-Opening of Formylcyclopropanes under IminiumIon Catalysis
(Wiley-VCH, 2018-04-12)
In this work, carboxylic acids, which are typically regarded as poor nucleophiles, are demonstrated to be competent reagents to promote the ring-opening of formylcyclopropanes after activation of the latter through iminium ...