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Enhancing polarization transfer from nitrogen-vacancy centers to external nuclear spins via dangling bond mediators
(Nature, 2024)
The use of nitrogen-vacancy (NV) centers in diamond as a non-invasive platform for hyperpolarizing nuclear spins in molecular samples is a promising area of research with the potential to enhance the sensitivity of nuclear ...
One- and Two-Electron Reductions in MiniSOG and their Implication in Catalysis
(Wiley, 2023-08)
The unconventional bioorthogonal catalytic activation of anticancer metal complexes by flavin and flavoproteins photocatalysis has been reported recently. The reactivity is based on a two-electron redox reaction of the ...
Competition between O–H and S–H intermolecular interactions in conformationally complex systems: The 2-Phenylethanethiol and 2-Phenylethanol dimers
(ACS, 2024-05)
Noncovalent interactions involving sulfur centers play a relevant role in biological and chemical environments. Yet, detailed molecular descriptions are scarce and limited to very simple model systems. Here we explore the ...