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Cryo-TEM assessment of droplet nucleation efficiency in hybrid acrylic/CeO2 semibatch miniemulsion polymerization
(ACS, 2014-11-26)
Monomer droplet nucleation has been successfully tracked in a seeded semibatch miniemulsion polymerization with miniemulsion feeding. Taking advantage of the marker capacity of CeO2 nanoparticles two polymerizations were ...
Hybrid acrylic/CeO2 nanocomposites using hydrophilic spherical and high aspect ratio CeO2 nanoparticles
(Royal Society of Chemistry, 2014-10-15)
A dispersion of CeO2 nanoparticles and nanorods stabilized with nitrilotriacetic acid (NTA) and a 4,4′-azobis(4-cyanovaleric acid) (V-501) initiator has been used to initiate the emulsion polymerization of acrylic monomers, ...
Particle nucleation and growth in seeded semibatch miniemulsion polymerization of hybrid CeO2/acrylic latexes
(2014-02-12)
CeO2/acrylic hybrid coatings with high solids content and with nanoparticle percentages up to 5 wt% have been successfully synthesized by seeded semibatch miniemulsion polymerization process. The droplet nucleation efficiency ...