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Experimental validation of a mathematical model for the evolution of the particle morphology of waterborne polymer-polymer hybrids: paving the way to the design and implementation of optimal polymerization strategies
(Elsevier, 2019-01-23)
Polymer-polymer composite nanoparticles allow both the improvement of the performance in stablished applications of waterborne polymer dispersions and targeting new applications that are out of reach of currently available ...
Kinetics of the Aqueous Phase Copolymerization of MAA and PEGMA Macromonomer: Influence of Monomer Concentration and Side Chain Length of PEGMA
(MDPI, 2017-04-20)
An in situ nuclear magnetic resonance spectroscopy (NMR) technique is used to monitor the aqueous-phase copolymerization kinetics of methacrylic acid (MAA) and poly(ethylene glycol) methyl ether methacrylate (PEGMA) ...
Dynamic Optimization and Non-linear Model Predictive Control to Achieve Targeted Particle Morphologies
(Wiley, 2019-03)
An event-driven approach based on dynamic optimization and nonlinear model predictive control (NMPC) is investigated together with inline Raman spectroscopy for process monitoring and control. The benefits and challenges ...
Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives
(MDPI, 2018-09)
A waterborne pressure-sensitive adhesive (PSA) that shows high adhesive performance and easy debondability on demand without leaving residues on the substrate (adhesive failure) has been developed. A key component of the ...
Stable Photocatalytic Paints Prepared from Hybrid Core-Shell Fluorinated/Acrylic/TiO2 Waterborne Dispersions
(MDPI, 2016-10-24)
The contamination of air and water is one of the major concerns towards the development of a sustainable world in the 21st century. In this context many efforts are devoted to the design of photocatalytic paints able to ...
Cryo-TEM assessment of droplet nucleation efficiency in hybrid acrylic/CeO2 semibatch miniemulsion polymerization
(ACS, 2014-11-26)
Monomer droplet nucleation has been successfully tracked in a seeded semibatch miniemulsion polymerization with miniemulsion feeding. Taking advantage of the marker capacity of CeO2 nanoparticles two polymerizations were ...
UV tunable biobased pressure sensitive adhesives containing piperonyl methacrylate
(ACS, 2019)
Novel waterborne pressure sensitive adhesives (PSA) with biobased contents up to 71%, and UV-light tunable features have been developed using piperonyl methacrylate as hard monomer. The biobased monomer was synthesized ...
UV screening clear coats based on encapsulated CeO2 hybrid latexes
(RSC, 2012-12-21)
CeO2 nanoparticles have been successfully incorporated into acrylic latex particles with an excellent homogeneous distribution (mostly one inorganic particle per polymer particle) and limited aggregation (inorganic ...