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1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis

dc.contributor.authorMielgo Vicente, María Antonia ORCID
dc.contributor.authorPalomo Nicolau, Claudio
dc.date.accessioned2018-03-16T09:09:25Z
dc.date.available2018-03-16T09:09:25Z
dc.date.issued2016-05-09
dc.identifier.citationBeilstein Journal of Organic Chemistry 12 : 918-936 (2016)es_ES
dc.identifier.issn1860-5397
dc.identifier.urihttp://hdl.handle.net/10810/25727
dc.description.abstractAsymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions.es_ES
dc.description.sponsorshipThe authors acknowledge the University of the Basque Country UPV/EHU (UFI 11/22), the Basque Government (Grant No IT-628-13) and the Ministerio de Economia y Competitividad (MEC, Grant CTQ2013-47925-C2-1-P), Spain for financial support.es_ES
dc.language.isoenges_ES
dc.publisherBeilstein Institutes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/CTQ2013-47925-C2-1-Pes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectasymmetric catalysises_ES
dc.subjectbifunctional catalystses_ES
dc.subject1H-imidazol-4(5H)-oneses_ES
dc.subjectpronucleophiles thiazol-4(5H)-oneses_ES
dc.subjectalpha-amino-acidses_ES
dc.subjectcarbon bond formationes_ES
dc.subjectenantioselective Michael additiones_ES
dc.subjectstereoselective-synthesises_ES
dc.subjectquaternary stereocenterses_ES
dc.subject1,4-addition reactiones_ES
dc.subjectchiral guanidineses_ES
dc.subjectgamma-additiones_ES
dc.subjectsoft enolizationes_ES
dc.subjectthiourea organocatalystses_ES
dc.title1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysises_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderThis is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), whichpermits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902076/es_ES
dc.identifier.doi10.3762/bjoc.12.90
dc.departamentoesQuímica orgánica Ies_ES
dc.departamentoeuKimika organikoa Ies_ES


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This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), whichpermits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Except where otherwise noted, this item's license is described as This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), whichpermits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.