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dc.contributor.authorAguado Ureta, Saioa
dc.contributor.authorRodríguez-Hernández, Juan
dc.contributor.authorDel Campo, Juan Adolfo
dc.contributor.authorPérez Álvarez, Leyre
dc.contributor.authorRuiz Rubio, Leire
dc.contributor.authorVilas Vilela, José Luis
dc.contributor.authorArtetxe Arretxe, Beñat
dc.contributor.authorReinoso Crespo, Santiago
dc.contributor.authorGutiérrez Zorrilla López, Juan Manuel
dc.date.accessioned2019-03-11T12:54:02Z
dc.date.available2019-03-11T12:54:02Z
dc.date.issued2018-03
dc.identifier.citationNanomaterials 8(3) : (2018) // Article ID 142es_ES
dc.identifier.issn2079-4991
dc.identifier.urihttp://hdl.handle.net/10810/31968
dc.description.abstractHerein we describe the preparation of hybrid polymer-inorganic interfaces by the immobilization of polyoxometalate nanoclusters on functionalized polymer surfaces. The polymeric surfaces were made of polystyrene-b-poly(acrylic acid)/polystyrene (PS-b-PAA/PS) blends by spin coating on a silicon wafer. The functionalization of the polymer film was obtained by interfacial migration of the amphiphilic block copolymer toward the interface upon water vapor annealing. The carboxylic acid functional groups contained in the PAA block were then employed to anchor the [Ln(III)(alpha-SiW11O39)](5-) polyoxometalates (Ln: Ce, Er). This purpose was achieved by immersing the films in aqueous solutions of the in situ-formed inorganic nanoclusters. X-ray photoelectron and confocal Raman spectroscopies, together with atomic force microscopy, confirmed the immobilization of the inorganic species at the interface.es_ES
dc.description.sponsorshipThis work has been financially supported by MINECO (grants MAT2010-17016 and MAT2010-21088-C03-01) and EJ/GV (IT477-10 and IT718-13; and ELKARTEK program (ACTIMAT)). The authors thank UPV/EHU for financial support (UFI11/53). S.A.-U. is indebted to UPV/EHU for her pre-doctoral fellowship. Technical and human support provided by SGIker (UPV/EHU) is gratefully acknowledged.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2010-17016es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2010-21088-C03-01es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectnanoclusteres_ES
dc.subjectpolyoxometalateses_ES
dc.subjectfunctionalized polymer surfaceses_ES
dc.subjectinterfacial migrationes_ES
dc.subjectcrystal-structureses_ES
dc.subjectbuilding-blockses_ES
dc.subjecthead groupses_ES
dc.subjectrare-earthes_ES
dc.subjectsilicaes_ES
dc.subjectclusterses_ES
dc.subjectnanoscalees_ES
dc.subjectcompositees_ES
dc.subjectcatalystes_ES
dc.subjectchainses_ES
dc.titleImmobilization of Polyoxometalates on Tailored Polymeric Surfaceses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://www.mdpi.com/2079-4991/8/3/142es_ES
dc.identifier.doi10.3390/nano8030142
dc.departamentoesQuímica físicaes_ES
dc.departamentoesQuímica inorgánicaes_ES
dc.departamentoeuKimika ez-organikoaes_ES
dc.departamentoeuKimika fisikoaes_ES


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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
Except where otherwise noted, this item's license is described as This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).