The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
dc.contributor.author | Ruiz Rubio, Leire | |
dc.contributor.author | Pérez Álvarez, Leyre | |
dc.contributor.author | Sánchez Bodón, Julia | |
dc.contributor.author | Arrighi, Valeria | |
dc.contributor.author | Vilas Vilela, José Luis | |
dc.date.accessioned | 2019-04-12T16:22:23Z | |
dc.date.available | 2019-04-12T16:22:23Z | |
dc.date.issued | 2019-01-07 | |
dc.identifier.citation | Materials 12(1) : (2019) // Article ID 167 | es_ES |
dc.identifier.issn | 1996-1944 | |
dc.identifier.uri | http://hdl.handle.net/10810/32454 | |
dc.description.abstract | Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture. | es_ES |
dc.description.sponsorship | This research was funded by the Government of Basque Country, grant ELKARTEK FRONTIERS KK-2017/0096 and grant Grupos de Investigacion IT718-13. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | poly(x-chlorostyrene) | es_ES |
dc.subject | honeycomb | es_ES |
dc.subject | breath figures | es_ES |
dc.subject | conformational entropy | es_ES |
dc.title | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.mdpi.com/1996-1944/12/1/167 | es_ES |
dc.identifier.doi | 10.3390/ma12010167 | |
dc.departamentoes | Química física | es_ES |
dc.departamentoeu | Kimika fisikoa | es_ES |
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Except where otherwise noted, this item's license is described as © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).