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dc.contributor.authorPérez Fernández, Iñigo
dc.contributor.authorSerrano Larrea, Edurne
dc.contributor.authorBazán Blau, Begoña del Pilar
dc.contributor.authorBarandika Argoitia, Miren Gotzone
dc.contributor.authorUrtiaga Greaves, Miren Karmele
dc.contributor.authorArriortua Marcaida, María Isabel
dc.date.accessioned2020-02-04T08:34:53Z
dc.date.available2020-02-04T08:34:53Z
dc.date.issued2019-11-09
dc.identifier.citationMolecules 24(22) : (2019) // Article ID 4059es_ES
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10810/40407
dc.descriptionThis article belongs to the Section Inorganic Chemistry.es_ES
dc.description.abstractIonothermal synthesis is a little used method for the preparation of coordination polymers. By this method, two cadmium compounds were synthesized, 1, with formula Cd-3(ox)F-2(Ina)(2) (Ina = isonicotinate) and 2, Cd(NO3)(2)(4,4 ' -Bpy) (4,4 ' -Bpy = 4,4 ' -Bipyridine). The modification of the reaction conditions has allowed to obtain 2 as a pure phase. The structure of both compounds was determined by a single-crystal X-ray diffraction. Compound 1 is isostructural to the previously reported Cd2Zn(ox)(OH)(2)(Ina)(2). It crystallizes in the monoclinic space group P2(1)/n and present a three-dimensional (3D) network, built-up from [Cd-3(ox)F-2](n)(2n+) layers, linked by isonicotinate ligands. Crystals of 2 are formed by twins of two components which are rotated ca. 180 degrees to each other. This compound crystallizes in the triclinic P-1 space group and its structure can be describe as a two-dimensional (2D) 4 connected 'sql' net. The layers are composed by [Cd(NO3)(2)](n) chains linked through 4,4 ' -Bpy ligands, and are pillared along the [011] direction. The thermal decomposition of 2 was studied by thermogravimetric and thermodiffractiometric techniques. The compound decomposes gradually starting from 160 degrees C, and due to heating, the structure suffers slight reversible changes in the bond distances and angles.es_ES
dc.description.sponsorshipThis research was funded by Spanish Ministry of Economy and Competitiveness (MINECO) through projects MAT2016-76739-R (AEI/FEDER, EU) and by the University of the Basque Country (UPV/EHU) through the GIU18/197 research group funding.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2016-76739-Res_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectcadmium coordination polymerses_ES
dc.subjectionothermal synthesises_ES
dc.subjectcrystal structure determinationes_ES
dc.subjectmetal-organic frameworkses_ES
dc.subjectmolecular recognitiones_ES
dc.subjectcrystal-structurees_ES
dc.subjectsymmetryes_ES
dc.subjectdesignes_ES
dc.subjectcationes_ES
dc.subjectshapees_ES
dc.titleIonothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis, Structural, and Thermal Characterizationes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly citedes_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://www.mdpi.com/1420-3049/24/22/4059es_ES
dc.identifier.doi10.3390/molecules24224059
dc.departamentoesMineralogía y petrologíaes_ES
dc.departamentoesQuímica inorgánicaes_ES
dc.departamentoeuKimika ez-organikoaes_ES
dc.departamentoeuMineralogia eta petrologiaes_ES


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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
Except where otherwise noted, this item's license is described as This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited