Pd(II)-Catalyzed C-H Acylation of (Hetero)arenes. Recent Advances
dc.contributor.author | Santiago Alvarez, Carlos | |
dc.contributor.author | Sotomayor Anduiza, María Nuria | |
dc.contributor.author | Lete Expósito, María Esther | |
dc.date.accessioned | 2020-08-03T11:56:49Z | |
dc.date.available | 2020-08-03T11:56:49Z | |
dc.date.issued | 2020-07-16 | |
dc.identifier.citation | Molecules 25(14) : (2020) // Article ID 3247 | es_ES |
dc.identifier.issn | 1420-3049 | |
dc.identifier.uri | http://hdl.handle.net/10810/45827 | |
dc.description.abstract | Di(hetero)aryl ketones are important motifs present in natural products, pharmaceuticals or agrochemicals. In recent years, Pd(II)-catalyzed acylation of (hetero)arenes in the presence of an oxidant has emerged as a catalytic alternative to classical acylation methods, reducing the production of toxic metal waste. Different directing groups and acyl sources are being studied for this purpose, although further development is required to face mainly selectivity problems in order to be applied in the synthesis of more complex molecules. Selected recent developments and applications are covered in this review. | es_ES |
dc.description.sponsorship | This work is supported by Ministerio de Economía y Competitividad (CTQ2016-74881-P), Ministerio de Ciencia e Innovación (PID2019-104148GB-I00) and Gobierno Vasco (IT1045-16). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-74881-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MCIU/PID2019-104148GB-I00 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | |
dc.subject | C-H activation | es_ES |
dc.subject | acylation | es_ES |
dc.subject | palladium | es_ES |
dc.subject | arenes | es_ES |
dc.subject | heteroarenes | es_ES |
dc.title | Pd(II)-Catalyzed C-H Acylation of (Hetero)arenes. Recent Advances | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2020-07-24T13:39:25Z | |
dc.rights.holder | © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/1420-3049/25/14/3247 | es_ES |
dc.identifier.doi | 10.3390/molecules25143247 | |
dc.departamentoes | Química orgánica II | |
dc.departamentoeu | Kimika organikoa II |
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Except where otherwise noted, this item's license is described as © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).