dc.contributor.author | Pérez Aguirre, Rubén | |
dc.contributor.author | Artetxe Arretxe, Beñat | |
dc.contributor.author | Beobide Pacheco, Garikoitz | |
dc.contributor.author | Castillo García, Oscar | |
dc.contributor.author | De Pedro, Imanol | |
dc.contributor.author | Luque Arrebola, Antonio | |
dc.contributor.author | Pérez Yáñez, Sonia | |
dc.contributor.author | Wuttke, Stefan | |
dc.date.accessioned | 2021-08-02T10:50:48Z | |
dc.date.available | 2021-08-02T10:50:48Z | |
dc.date.issued | 2021-05-19 | |
dc.identifier.citation | Cell Reports Physical Science 2(5) : (2021) // Article ID 100421 | es_ES |
dc.identifier.issn | 2666-3864 | |
dc.identifier.uri | http://hdl.handle.net/10810/52623 | |
dc.description.abstract | [EN] Capture and sensing of emerging pollutants is one of the increasing environmental concerns due to the adverse ecological and human health effects. Here, we report the synthesis of a supramolecular metal-organic framework (SMOF) [CrCu6(m-H2O)6(m3-OH)6(m-adeninato-kN33:kN9)6](SO4)1.5 which is able to capture anionic drugs and exhibits magnetic properties useful for sensing purposes. The features of the nucleobase decorated CrCu6 building block allow the incorporation of up to 9 drug molecules (i.e., ibuprofen and naproxen in this work) per heptameric entity. In addition, we provide a simple way to quantify the incorporated number of drug molecules through a magnetic sustentation experiment in which the field required to keep the particles attached to the electromagnet pole is linearly related to the total mass of the anionic counterion. In this way, it also provides an easy way to determine the amount of entrapped drug molecules, making this SMOF a promising candidate for environmental remediation technologies. | es_ES |
dc.description.sponsorship | This work has been funded by the Universidad del Pais Vasco/Euskal Herriko Unibertsitatea (GIU17/50), the Gobierno Vas-co/Eusko Jaurlaritza (PIBA18/14; IT1291-19), the Ministerio de Economia y Competitividad (MAT2016-75883-C2-1P), the Ministerio de Ciencia e Innovacion (PID2019-108028GB-C21), and FEDER funds. Technical and human support provided by SGIker (UPV/EHU, MICINN, GV/EJ, and ESF) is also acknowledged. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier ; Cell Press | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/PID2019-108028GB-C21 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/MAT2016-75883-C2-1P | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.title | Ferromagnetic supramolecular metal-organic frameworks for active capture and magnetic sensing of emerging drug pollutants | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | ©2021 The Author(s). This article is available under the Creative Commons CC-BY-NC-ND license and permits non-commercial use of the work as published, without adaptation or alteration provided the work is fully attributed. | es_ES |
dc.rights.holder | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S2666386421001119 | es_ES |
dc.identifier.doi | 10.1016/j.xcrp.2021.100421 | |
dc.departamentoes | Química Orgánica e Inorgánica | es_ES |
dc.departamentoeu | Kimika Organikoa eta Ez-Organikoa | es_ES |