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dc.contributor.authorNiemczyk, Edyta M.
dc.contributor.authorGómez López, Álvaro ORCID
dc.contributor.authorHaler, Jean R. N.
dc.contributor.authorFrache, Gilles
dc.contributor.authorSardon Muguruza, Haritz
dc.contributor.authorQuintana, Robert
dc.date.accessioned2021-09-16T10:09:48Z
dc.date.available2021-09-16T10:09:48Z
dc.date.issued2021-08-25
dc.identifier.citationPolymers 13(17) : (2021) // Article ID 2856es_ES
dc.identifier.issn2073-4360
dc.identifier.urihttp://hdl.handle.net/10810/53104
dc.description.abstractPlasma-induced free-radical polymerizations rely on the formation of radical species to initiate polymerization, leading to some extent of monomer fragmentation. In this work, the plasma-induced polymerization of an allyl ether-substituted six-membered cyclic carbonate (A6CC) is demonstrated and emphasizes the retention of the cyclic carbonate moieties. Taking advantage of the low polymerization tendency of allyl monomers, the characterization of the oligomeric species is studied to obtain insights into the effect of plasma exposure on inducing free-radical polymerization. In less than 5 min of plasma exposure, a monomer conversion close to 90% is obtained. The molecular analysis of the oligomers by gel permeation chromatography coupled with high-resolution mass spectrometry (GPC-HRMS) further confirms the high preservation of the cyclic structure and, based on the detected end groups, points to hydrogen abstraction as the main contributor to the initiation and termination of polymer chain growth. These results demonstrate that the elaboration of surfaces functionalized with cyclic carbonates could be readily elaborated by atmospheric-pressure plasmas, for instance, by copolymerization.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/
dc.subjectallyl-substituted cyclic carbonatees_ES
dc.subjectfree-radical polymerizationes_ES
dc.subjectatmospheric-pressure plasmaes_ES
dc.titleInsights on the Atmospheric-Pressure Plasma-Induced Free-Radical Polymerization of Allyl Ether Cyclic Carbonate Liquid Layerses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.date.updated2021-09-09T13:47:34Z
dc.rights.holder2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/es_ES
dc.relation.publisherversionhttps://www.mdpi.com/2073-4360/13/17/2856/htmes_ES
dc.identifier.doi10.3390/polym13172856
dc.departamentoesPolímeros y Materiales Avanzados: Física, Química y Tecnología
dc.departamentoeuPolimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia


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2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/
Except where otherwise noted, this item's license is described as 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/