dc.contributor.author | Jamil, Rabia | |
dc.contributor.author | Tomé, Liliana C. | |
dc.contributor.author | Mecerreyes Molero, David | |
dc.contributor.author | Silvester, Debbie S. | |
dc.date.accessioned | 2022-02-11T08:42:31Z | |
dc.date.available | 2022-02-11T08:42:31Z | |
dc.date.issued | 2021-10 | |
dc.identifier.citation | Australian Journal of Chemistry 74(11) : 767-777 (2021) | es_ES |
dc.identifier.issn | 0004-9425 | |
dc.identifier.issn | 1445-0038 | |
dc.identifier.uri | http://hdl.handle.net/10810/55431 | |
dc.description.abstract | [EN] In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application includematerials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4](-), [PF6](-), and [Tf2N](-). The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications. | es_ES |
dc.description.sponsorship | D.S.S. thanks the Australian Research Council for funding through a Future Fellowship (FT170100315). DM thanks the Agencia Española de Investigacion (AEI) for funding through project PID2020-119026GB-I00. LCT is grateful to FCT (Fundacao para a Ciencia e a Tecnologia) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND). Associate Laboratory for Green Chemistry - LAQValso acknowledge the financial support from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | CSIRO | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2020-119026GB-I00 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | ionic liquids | es_ES |
dc.subject | polymers | es_ES |
dc.subject | CO2 fixation | es_ES |
dc.subject | cycloaddition reaction | es_ES |
dc.subject | heterogeneous catalysis | es_ES |
dc.subject | poly(ionic liquids) | es_ES |
dc.subject | CO2 conversion | es_ES |
dc.subject | catalysts | es_ES |
dc.title | Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments* | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © CSIRO 2021 Open Access CC BY | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.publish.csiro.au/ch/Fulltext/CH21182 | es_ES |
dc.identifier.doi | 10.1071/CH21182 | |