A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls
dc.contributor.author | Echenique Errandonea, Estitxu | |
dc.contributor.author | López-Vargas, Mireya E. | |
dc.contributor.author | Pérez, Juana M. | |
dc.contributor.author | Rojas, Sara | |
dc.contributor.author | Choquesillo Lazarte, Duane | |
dc.contributor.author | Seco Botana, José Manuel ![]() | |
dc.contributor.author | Fernández, Ignacio | |
dc.contributor.author | Rodríguez-Diéguez, Antonio | |
dc.date.accessioned | 2022-03-31T11:56:45Z | |
dc.date.available | 2022-03-31T11:56:45Z | |
dc.date.issued | 2022-03-06 | |
dc.identifier.citation | Catalysts 12(3) : (2022) // Article ID 299 | es_ES |
dc.identifier.issn | 2073-4344 | |
dc.identifier.uri | http://hdl.handle.net/10810/56153 | |
dc.description.abstract | Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n (in advance, namely Y/Eu-MOF), is described. The three-dimensional structure has been synthesized by solvothermal routes and thoroughly characterized, by means of single crystal X-ray diffraction, powder X-ray diffraction, electronic microscopy, ICP-AES, electrophoretic mobility, and FTIR spectra. Intriguingly, the porous nature allows for coordinated solvent molecules displacement, yielding unsaturated metal centers, which can act as a Lewis acid catalyst. This novel supramolecular entity has been tested in cyanosilylation and hydroboration reactions on carbonyl substrates of a diverse nature, exhibiting an extraordinary activity. | es_ES |
dc.description.sponsorship | This research has been funded by the State Research Agency (grants CTQ2017-84334-R and PGC2018-102052-B-C21) of the Spanish Ministry of Science, Innovation and Universities, the European Union (European Regional Development Fund—ERDF), Junta de Andalucía (P20_01041, UAL2020-AGR-B1781, B-FQM-734-UGR20 and FQM-394). E.E., S.R., and J.P. acknowledge the Government of the Basque Country, Juan de la Cierva Incorporación (grant no. IJC2019-038894-I) and University of Almeria (grant no. HIPATIA2021_04) for their respective fellowships. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/CTQ2017-84334-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PGC2018-102052-B-C21 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | |
dc.subject | heterobimetallic | es_ES |
dc.subject | metal-organic framework | es_ES |
dc.subject | cyanosilylation | es_ES |
dc.subject | hydroboration | es_ES |
dc.subject | yttrium | es_ES |
dc.subject | europium | es_ES |
dc.title | A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2022-03-24T14:47:02Z | |
dc.rights.holder | 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/2073-4344/12/3/299/htm | es_ES |
dc.identifier.doi | 10.3390/catal12030299 | |
dc.departamentoes | Química aplicada | |
dc.departamentoeu | Kimika aplikatua |
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Except where otherwise noted, this item's license is described as 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).