One-Step Lignin Refining Process: The Influence of the Solvent Nature on the Properties and Quality of Fractions
dc.contributor.author | Gordobil Goñi, Oihana | |
dc.contributor.author | Díaz Herrera, René | |
dc.contributor.author | sandak, jakub | |
dc.contributor.author | Sandak, Anna | |
dc.date.accessioned | 2022-08-08T09:18:29Z | |
dc.date.available | 2022-08-08T09:18:29Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Polymers 14(12) : (2022) // Article ID 2363 | es_ES |
dc.identifier.issn | 2073-4360 | |
dc.identifier.uri | http://hdl.handle.net/10810/57247 | |
dc.description.abstract | Heterogeneity of kraft lignin is one of the main limitations for the development of high-performance applications. Therefore, refining lignin using organic solvents is a promising strategy to obtain homogenous fractions with controlled quality in terms of structure and properties. In this work, one-step refining processes for hardwood kraft lignin using nine organic solvents of different chemical nature and polarity were carried out with the aim of investigating and understanding the effect of the type of organic solvent on the quality of resulting fractions. Structural features of both soluble and insoluble lignin fractions were assessed by GPC, Py-GC-MS, and FTIR linked to PCA analysis. Moreover, functional properties such as physical appearance, hygroscopicity, antioxidant capacity, and thermal properties were evaluated. The results evidenced the relationship between the nature and polarity of the solvents and the properties of the obtained soluble and insoluble fractions. | es_ES |
dc.description.sponsorship | This research was funded by the European Commission’s funding of the InnoRenew project (Grant Agreement #739574 under the Horizon 2020 WIDESPREAD-2-Teaming program) and the Republic of Slovenia (investment funding from the Republic of Slovenia and the European Regional Development Fund). O.G. is grateful for the financial support received from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Action for development of the BIO4CARE project (Grant Number #101023389). R.H. received funding from the Spanish Ministry of Science and Innovation and the University of the Basque Country UPV/EHU (POSTDOC: IJC2020-043740-I). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/739574 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/101023389 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.subject | hardwood kraft lignin | es_ES |
dc.subject | one-step fractionation | es_ES |
dc.subject | organic solvents | es_ES |
dc.subject | hygroscopicity | es_ES |
dc.subject | thermal properties | es_ES |
dc.subject | antioxidant capacity | es_ES |
dc.title | One-Step Lignin Refining Process: The Influence of the Solvent Nature on the Properties and Quality of Fractions | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2022-06-23T12:22:26Z | |
dc.rights.holder | © 2022 by the authors.Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/2073-4360/14/12/2363 | es_ES |
dc.identifier.doi | 10.3390/polym14122363 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Ingeniería química y del medio ambiente | |
dc.departamentoeu | Ingeniaritza kimikoa eta ingurumenaren ingeniaritza |
Files in this item
This item appears in the following Collection(s)
Except where otherwise noted, this item's license is described as © 2022 by the authors.Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).