Remote near-field spectroscopy of vibrational strong coupling between organic molecules and phononic nanoresonators
dc.contributor.author | Dolado, Irene | |
dc.contributor.author | Maciel Escudero, Carlos | |
dc.contributor.author | Nikulina, Elizaveta | |
dc.contributor.author | Modin, Evgenii | |
dc.contributor.author | Calavalle, Francesco | |
dc.contributor.author | Chen, Su | |
dc.contributor.author | Bylinkin, Andrei | |
dc.contributor.author | Alfaro Mozaz, Francisco Javier | |
dc.contributor.author | Li, Jiahan | |
dc.contributor.author | Edgar, James H. | |
dc.contributor.author | Casanova Fernández, Félix | |
dc.contributor.author | Vélez, Saül | |
dc.contributor.author | Hueso Arroyo, Luis Eduardo | |
dc.contributor.author | Esteban Llorente, Rubén | |
dc.contributor.author | Aizpurua Iriazabal, Francisco Javier | |
dc.contributor.author | Hillenbrand, Rainer | |
dc.date.accessioned | 2022-12-16T16:45:28Z | |
dc.date.available | 2022-12-16T16:45:28Z | |
dc.date.issued | 2022-11 | |
dc.identifier.citation | Nature Communications 13(1) : (2022) // Article ID 6850 | es_ES |
dc.identifier.issn | 2041-1723 | |
dc.identifier.uri | http://hdl.handle.net/10810/58851 | |
dc.description.abstract | Vibrational strong coupling (VSC) promises ultrasensitive IR spectroscopy and modification of material properties. Here, nanoscale mapping of VSC between organic molecules and individual IR nanoresonators is achieved by remote near-field spectroscopy. Phonon polariton (PhP) nanoresonators can dramatically enhance the coupling of molecular vibrations and infrared light, enabling ultrasensitive spectroscopies and strong coupling with minute amounts of matter. So far, this coupling and the resulting localized hybrid polariton modes have been studied only by far-field spectroscopy, preventing access to modal near-field patterns and dark modes, which could further our fundamental understanding of nanoscale vibrational strong coupling (VSC). Here we use infrared near-field spectroscopy to study the coupling between the localized modes of PhP nanoresonators made of h-BN and molecular vibrations. For a most direct probing of the resonator-molecule coupling, we avoid the direct near-field interaction between tip and molecules by probing the molecule-free part of partially molecule-covered nanoresonators, which we refer to as remote near-field probing. We obtain spatially and spectrally resolved maps of the hybrid polariton modes, as well as the corresponding coupling strengths, demonstrating VSC on a single PhP nanoresonator level. Our work paves the way for near-field spectroscopy of VSC phenomena not accessible by conventional techniques. | es_ES |
dc.description.sponsorship | This work was supported by the MCIN/AEI/10.13039/501100011033 under the María de Maeztu Units of Excellence Program (CEX2020-001038-M) and the Projects RTI2018-094830-B-100, PID2021-123949OB-I00, PID2019-107432GB-I00 and PID2021-122511OB-I00, as well as by the Graphene Flagship (GrapheneCore3, No. 881603). J.L. and J.H.E. are grateful for support from the Office of Naval Research (Award No. N00014-20-1-2474), for the BN crystal growth. S.V. acknowledges financial support by the Comunidad de Madrid through the Atracción de Talento program (grant no. 2020-T1/IND-20041). C.M.-E., R.E., and J.A. received funding from grant no. IT 1526-22 from the Basque Government for consolidated groups of the Basque University. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Nature | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/CEX2020-001038-M | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/RTI2018-094830-B-100 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2021-123949OB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2019-107432GB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2021-122511OB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/881603 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | polaritons | es_ES |
dc.subject | scattering | es_ES |
dc.title | Remote near-field spectroscopy of vibrational strong coupling between organic molecules and phononic nanoresonators | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © The Author(s) 2022. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.nature.com/articles/s41467-022-34393-4 | es_ES |
dc.identifier.doi | 10.1038/s41467-022-34393-4 | |
dc.contributor.funder | European Commission |
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