dc.contributor.author | Pérez Galera, Juana María | |
dc.contributor.author | Morales Cámara, Samuel | |
dc.contributor.author | García Salas, Fernando M. | |
dc.contributor.author | Ruiz Cuevas, Noelia | |
dc.contributor.author | López Vargas, Mireya | |
dc.contributor.author | Choquesillo Lazarte, Duane | |
dc.contributor.author | Cepeda Ruiz, Javier | |
dc.contributor.author | García, José Antonio | |
dc.contributor.author | Abdelkader Fernández, Víctor Karim | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.contributor.author | Rojas, Sara | |
dc.contributor.author | Fernández, Ignacio | |
dc.date.accessioned | 2023-01-25T17:16:37Z | |
dc.date.available | 2023-01-25T17:16:37Z | |
dc.date.issued | 2022-11 | |
dc.identifier.citation | Crystal Growth & Design 22(12) : 7395–7404 (2022) | es_ES |
dc.identifier.issn | 1528-7483 | |
dc.identifier.issn | 1528-7505 | |
dc.identifier.uri | http://hdl.handle.net/10810/59480 | |
dc.description.abstract | A new family of metal–organic frameworks (MOFs) named GR-MOFs with the chemical formula {[Mx(BCA)y](H2O)z(DMF)w} (x,y,z,w: 1,1,2,0; 1,1.5,0,1; 1,2,2,1; and 1,1,0,2 for GR-MOF-11 to 14, respectively) based on s-block [M: Sr (GR-MOF-11), Ba (GR-MOF-14)] and d-block [M: Y (GR-MOF-12) and Cd (GR-MOF-13)] metals together with the biquinoline ligand 2,2′-bicinchoninic acid (H2BCA) has been synthetized by a solvothermal route and fully characterized by elemental and thermogravimetric analysis, Fourier transform infrared spectroscopy, photoluminescence, particle size distribution through optical microscopy, electrophoretic mobility, and finally, X-ray single-crystal and powder diffraction. The structural characterization reveals that these 2D and 3D MOFs possess a rich variety of coordination modes that maintained the Janus-head topology on the ligand in most of the cases. The new MOFs were studied in the catalyzed cyanosilylation and hydroboration of an extensive group of aldehydes and ketones, wherein the s-block metal-based MOFs GR-MOF-11 and GR-MOF-14 provided the highest efficiency ever reported in the MOF-catalyzed cyanosilylation of carbonyl compounds by using only 0.5 mol % of catalyst loading, room temperature, and solvent-free conditions. Furthermore, the hydroboration of ketones has been reported for the first time with this type of s-block metal catalysts obtaining from moderate to good conversions. | es_ES |
dc.description.sponsorship | This research has been funded by the grants CTQ2017-84334 R, PGC2018-102052 B-C21, and PGC2018-102052 A-C22 funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe”, Junta de Andalucía (102C2000004, CV20-78799, P20_01041, UAL-FEDER UAL2020-AGR-B1781, FEDER 2014–2020 A-RNM-433-UGR18, ProyExcel_00386, ProyExcel_00105, B-FQM-734-UGR20, FQM-376, and FQM-394), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22, IT1500-22), and Gobierno de España MCIN/AEI/10.13039/501100011033/Unión Europea “Next GenerationEU”/PRTR (programs PDC2021-121248-I00 and PLEC2021-007774). S.R. acknowledges the Juan de la Cierva Incorporación Fellowship (grant agreement no. IJC2019-038894-I) and J.M.P., a Hipatia fellowship (University of Almería). The authors acknowledge Manuel Pérez Mendoza from the University of Granada for his collaboration. Funding for open access charge: Universidad de Granada/CBUA. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2017-84334 R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PDC2021-121248-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PLEC2021-007774 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/IJC2019-038894-I | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | catalysts | es_ES |
dc.subject | ligands | es_ES |
dc.subject | metal–organic frameworks | es_ES |
dc.subject | metals | es_ES |
dc.subject | molecules | es_ES |
dc.title | Metal-Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2022 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/full/10.1021/acs.cgd.2c00985 | es_ES |
dc.identifier.doi | 10.1021/acs.cgd.2c00985 | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |