Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
dc.contributor.author | Echenique Errandonea, Estitxu | |
dc.contributor.author | Rojas, Sara | |
dc.contributor.author | Cepeda Ruiz, Javier | |
dc.contributor.author | Choquesillo Lazarte, Duane | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.contributor.author | Seco Botana, José Manuel ![]() | |
dc.date.accessioned | 2023-02-24T15:42:46Z | |
dc.date.available | 2023-02-24T15:42:46Z | |
dc.date.issued | 2023-02-15 | |
dc.identifier.citation | Molecules 28(4) : (2023) // Article ID 1846 | es_ES |
dc.identifier.issn | 1420-3049 | |
dc.identifier.uri | http://hdl.handle.net/10810/60072 | |
dc.description.abstract | As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H2O}n chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (ac) signals under zero direct current (dc) magnetic field, whereas single-molecule magnet behaviour is achieved when CoII ions are diluted in a ZnII based matrix. Interestingly, this strategy renders a bifunctional [CoxZn1-xL]n material that is also characterized by a strong photoluminescent emitting capacity. | es_ES |
dc.description.sponsorship | Financial support was given by Junta de Andalucía (Spain) (B-FQM-734-UGR20, ProyExcel_00386 and FQM-394), University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22), and the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22 and PGC2018-102052-B-C21). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.subject | metal-organic framework | es_ES |
dc.subject | cobalt-zinc bifunctionality | es_ES |
dc.subject | induced molecular magnetism | es_ES |
dc.subject | photoluminescent properties | es_ES |
dc.title | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2023-02-24T14:08:53Z | |
dc.rights.holder | © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/1420-3049/28/4/1846 | es_ES |
dc.identifier.doi | 10.3390/molecules28041846 | |
dc.departamentoes | Química aplicada | |
dc.departamentoeu | Kimika aplikatua |
Files in this item
This item appears in the following Collection(s)
Except where otherwise noted, this item's license is described as © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).