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Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions

dc.contributor.authorEchenique Errandonea, Estitxu
dc.contributor.authorRojas, Sara
dc.contributor.authorCepeda Ruiz, Javier
dc.contributor.authorChoquesillo Lazarte, Duane
dc.contributor.authorRodríguez Diéguez, Antonio
dc.contributor.authorSeco Botana, José Manuel ORCID
dc.date.accessioned2023-02-24T15:42:46Z
dc.date.available2023-02-24T15:42:46Z
dc.date.issued2023-02-15
dc.identifier.citationMolecules 28(4) : (2023) // Article ID 1846es_ES
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10810/60072
dc.description.abstractAs a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H2O}n chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (ac) signals under zero direct current (dc) magnetic field, whereas single-molecule magnet behaviour is achieved when CoII ions are diluted in a ZnII based matrix. Interestingly, this strategy renders a bifunctional [CoxZn1-xL]n material that is also characterized by a strong photoluminescent emitting capacity.es_ES
dc.description.sponsorshipFinancial support was given by Junta de Andalucía (Spain) (B-FQM-734-UGR20, ProyExcel_00386 and FQM-394), University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22), and the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22 and PGC2018-102052-B-C21).es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22es_ES
dc.relationinfo:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectmetal-organic frameworkes_ES
dc.subjectcobalt-zinc bifunctionalityes_ES
dc.subjectinduced molecular magnetismes_ES
dc.subjectphotoluminescent propertieses_ES
dc.titleSlow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ionses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.date.updated2023-02-24T14:08:53Z
dc.rights.holder© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).es_ES
dc.relation.publisherversionhttps://www.mdpi.com/1420-3049/28/4/1846es_ES
dc.identifier.doi10.3390/molecules28041846
dc.departamentoesQuímica aplicada
dc.departamentoeuKimika aplikatua


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© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).
Except where otherwise noted, this item's license is described as © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).