Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
dc.contributor.author | Criado González, Miryam | |
dc.contributor.author | Alegret Ramón, Nuria | |
dc.contributor.author | Fracaroli, Alejandro M. | |
dc.contributor.author | Mantione, Daniele | |
dc.contributor.author | Guzmán González, Gregorio | |
dc.contributor.author | Del Olmo Martínez, Rafael ![]() | |
dc.contributor.author | Tashiro, Kentaro | |
dc.contributor.author | Tomé, Liliana C. | |
dc.contributor.author | Picchio, Matías L. | |
dc.contributor.author | Mecerreyes Molero, David | |
dc.date.accessioned | 2023-06-28T18:18:44Z | |
dc.date.available | 2023-06-28T18:18:44Z | |
dc.date.issued | 2023-06 | |
dc.identifier.citation | Angewandte Chemie International Edition 62(26) : (2023) // Article ID e202301489 | es_ES |
dc.identifier.issn | 1433-7851 | |
dc.identifier.issn | 1521-3773 | |
dc.identifier.uri | http://hdl.handle.net/10810/61781 | |
dc.description.abstract | Eutectogels are an emerging family of soft ionic materials alternative to ionic liquid gels and organogels, offering fresh perspectives for designing functional dynamic platforms in water-free environments. Herein, the first example of mixed ionic and electronic conducting supramolecular eutectogel composites is reported. A fluorescent glutamic acid-derived low-molecular-weight gelator (LMWG) was found to self-assemble into nanofibrillar networks in deep eutectic solvents (DES)/poly(3,4-ethylenedioxythiophene) (PEDOT): chondroitin sulfate dispersions. These dynamic materials displayed excellent injectability and self-healing properties, high ionic conductivity (up to 10−2 S cm−1), good biocompatibility, and fluorescence imaging ability. This set of features turns the mixed conducting supramolecular eutectogels into promising adaptive materials for bioimaging and electrostimulation applications. | es_ES |
dc.description.sponsorship | This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under the grant agreement No 823989 “IONBIKE”. The financial support received from CONICET and ANPCyT (Argentina) is also gratefully acknowledged. M. C.-G. thanks Emakiker Grant Program of POLYMAT. L. C. T. is grateful to Fundação para a Ciência e a Tecnologia (FCT/MCTES) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND), and Associate Laboratory for Green Chemistry—LAQV, which is also financed by FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020). D. M. thanks “Ayuda RYC2021-031668-I financiada por MCIN/AEI/10.13039/501100011033 y por la Unión Europea NextGenerationEU/PRTR”. The authors thank the technical and human support provided by SGIker (UPV/EHU/ERDF, EU). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/823989 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/RYC2021-031668-I | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | bioimaging | es_ES |
dc.subject | deep eutectic solvents | es_ES |
dc.subject | ionic liquids | es_ES |
dc.subject | organic mixed ionic–electronic conductors | es_ES |
dc.subject | supramolecular eutectogels | es_ES |
dc.title | Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. | es_ES |
dc.rights.holder | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202301489 | es_ES |
dc.identifier.doi | 10.1002/anie.202301489 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |
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This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.