dc.contributor.author | Díaz, Estibaliz | |
dc.contributor.author | Reyes Martín, Efraim | |
dc.contributor.author | Uria Pujana, Uxue ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Carrillo Fernández, María Luisa ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Tejero, Tomás | |
dc.contributor.author | Merino, Pedro | |
dc.contributor.author | Vicario Hernando, José Luis ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.date.accessioned | 2023-12-01T09:54:21Z | |
dc.date.available | 2023-12-01T09:54:21Z | |
dc.date.issued | 2018-04-12 | |
dc.identifier.citation | Chemistry - A European Journal 24(35) : 8764-8768(2018) | es_ES |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.uri | http://hdl.handle.net/10810/63299 | |
dc.description.abstract | In this work, carboxylic acids, which are typically regarded as poor nucleophiles, are demonstrated to be competent reagents to promote the ring-opening of formylcyclopropanes after activation of the latter through iminium ion formation. Under optimized reaction conditions, a variety of γ-acyloxy-substituted aldehydes can be obtained in high yields and enantioselectivities through the desymmetrization of substituted meso-formylcyclopropanes in the presence of a chiral secondary amine as catalys | es_ES |
dc.description.sponsorship | Spanish MINECO(FEDER-CTQ2017-83633-P and FEDER-CTQ2016-76155-R),Basque Government (IT908-16),UPV/EHU (fellowship to E. D.) and Government of Aragon. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley-VCH | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2017-83633-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-76155-R | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.subject | asymmetric catalysis | es_ES |
dc.subject | carboxylicacids | es_ES |
dc.subject | cyclopropanes | es_ES |
dc.subject | organocatalysis | es_ES |
dc.subject | strained molecules | es_ES |
dc.title | Carboxylates as Nucleophiles in the Enantioselective Ring-Opening of Formylcyclopropanes under IminiumIon Catalysis | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
dc.relation.publisherversion | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201801434 | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/chem.201801434 | es_ES |
dc.identifier.doi | 10.1002/chem.201801434 | |
dc.departamentoes | Química orgánica II | es_ES |
dc.departamentoeu | Kimika organikoa II | es_ES |