dc.contributor.author | Barbolla Cuadrado, Iratxe | |
dc.contributor.author | Sotomayor Anduiza, María Nuria | |
dc.contributor.author | Lete Expósito, María Esther | |
dc.date.accessioned | 2024-01-22T13:27:38Z | |
dc.date.available | 2024-01-22T13:27:38Z | |
dc.date.issued | 2020-07-28 | |
dc.identifier.citation | Arkivoc 7 : 158-179 (2020) | es_ES |
dc.identifier.issn | 1551-7012 | |
dc.identifier.issn | 1551-7004 | |
dc.identifier.uri | http://hdl.handle.net/10810/64178 | |
dc.description.abstract | Guanidines have received great attention due to their application as superbasic proton sponges and
organocatalysts, as well as excellent N-donor ligands able to coordinate with different metals. The
introduction of different substituents can modulate the basicity/nucleophilicity of the guanidines, their
coordination ability, and thus, the electronic and steric properties of their metal complexes, regulating their
catalytic activity. This review presents recent developments on guanidine-based ligand families
[monoguanidine, bis(guanidine) and hybrid guanidine ligands], highlighting their potential in transition metalcatalyzed
reactions. | es_ES |
dc.description.sponsorship | Ministerio de Economía y Competitividad (CTQ2016-74881-P), Gobierno Vasco (IT1045-16) | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | ARKAT USA | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-74881-P | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | guanidine | es_ES |
dc.subject | metal-catalyzed reactions | es_ES |
dc.subject | asymmetric catalysis | es_ES |
dc.subject | transition metals | es_ES |
dc.title | Transition metal-guanidine complexes as catalysts in organic reactions. Recent developments | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © AUTHOR(S). This paper is an open access article distributed under the terms of the Creative Commons Attribution (CC BY)
license (http://creativecommons.org/licenses/by/4.0/) | es_ES |
dc.relation.publisherversion | https://doi.org/10.24820/ark.5550190.p011.265 | es_ES |
dc.identifier.doi | 10.24820/ark.5550190.p011.265 | |
dc.departamentoes | Química Orgánica e Inorgánica | es_ES |
dc.departamentoeu | Kimika Organikoa eta Ez-Organikoa | es_ES |