dc.contributor.author | Cepeda Ruiz, Javier | |
dc.contributor.author | Pérez Mendoza, Manuel | |
dc.contributor.author | Calahorro, Antonio J. | |
dc.contributor.author | Casati, Nicola | |
dc.contributor.author | Seco Botana, José Manuel ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Aragones Anglada, Marta | |
dc.contributor.author | Peyman, Z. Moghadam | |
dc.contributor.author | Fairen-Jimenez, David | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.date.accessioned | 2024-01-24T17:11:24Z | |
dc.date.available | 2024-01-24T17:11:24Z | |
dc.date.issued | 2018-08-08 | |
dc.identifier.citation | Journal of Materials Chemistry A 6(36) : 17409-17416 (2018) | es_ES |
dc.identifier.issn | 2050-7488 | |
dc.identifier.issn | 2050-7496 | |
dc.identifier.uri | http://hdl.handle.net/10810/64299 | |
dc.description.abstract | We report the synthesis of a new family of four new isoreticular metal–organic frameworks (MOFs) based on
Cu–Cu paddle-wheel building units. The four MOFs contain 1D microchannels modulated by chemical
functionalisation of a dicarboxylate ligand or the use of different bis-4,40-pyridyl-like connectors
behaving as ancillary linkers. A deep analysis of their CO2, H2 and CH4 adsorption properties, combining
both experimental and grand canonical Monte Carlo isotherms as well as in situ synchrotron X-ray
diffraction, shows variable adsorption behaviour towards the studied gases, with some materials acting
as molecular sieves with virtually infinite selectivity. | es_ES |
dc.description.sponsorship | This work was supported by the Junta de Andalucía (FQM-1484), Red Guipuzcoana de Ciencia, Tecnolgía e Innovación (OF188/2017) and University of the Basque Country (GIU14/01, GIU17/013, EHUA16/32). The authors acknowledge technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). D. F.-J. thanks the Royal Society for funding through a University Research Fellowship and the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (NanoMOFdeli), ERC-2016-COG 726380. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | RSC | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.title | Modulation of Pore Shape and Adsorption Selectivity by Ligand Functionalization in a Series of “rob”-like Flexible Metal-Organic Frameworks | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © The Royal Society of Chemistry 2018 | es_ES |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2018/ta/c8ta04316g | es_ES |
dc.identifier.doi | 10.1039c8ta04316g | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |