dc.contributor.author | Hernández Ramos, Fabio ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Fernández Rodríguez, Javier | |
dc.contributor.author | González Alriols, María | |
dc.contributor.author | Labidi Bouchrika, Jalel | |
dc.contributor.author | Erdocia Iriarte, Xabier | |
dc.date.accessioned | 2024-02-08T08:03:54Z | |
dc.date.available | 2024-02-08T08:03:54Z | |
dc.date.issued | 2020-07-13 | |
dc.identifier.citation | Fuel 280 : (2020) // Article ID 118524 | |
dc.identifier.issn | 0016-2361 | |
dc.identifier.issn | 1873-7153 | |
dc.identifier.uri | http://hdl.handle.net/10810/64881 | |
dc.description.abstract | The aim of this work was to study the influence of a renewable capping agent (CA) in the production of monomeric compounds from the depolymerization of an organosolv lignin (Pinus radiata) by a base catalyzed depolymerization (BCD) process. After the delignification process of the Pinus radiata sawdust, the lignin contained in the black liquor was subjected to a first mild depolymerization process, without using any catalyst, in order to obtain two different products: a lignin which was the feed in the subsequent BCD process and a phenolic oil which was used as CA in the same BCD process. This process was carried out at 230 °C in three consecutive cycles of 20 min using different amounts of capping agent dissolved in a 4% wt. NaOH solution with a lignin:solvent ratio of 1:20. The use of a renewable capping agent derived from lignin was effective not only in terms of phenolic oil production increasing but also in maximizing the monomeric phenolic compounds concentration. The use of CA: lignin ratio of 1:1 resulted the most effective with 10.64% of oil yield and almost 44% of monomeric phenolic compounds concentration while minimizing de undesired by-products yield. | es_ES |
dc.description.sponsorship | This work was financially supported by the Spanish Ministry of Science, Innovation and Universities (CTQ2016-78689-R) | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-78689-R | |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | lignin | es_ES |
dc.subject | capping agent | es_ES |
dc.subject | depolymerization | es_ES |
dc.subject | phenolic monomers | es_ES |
dc.subject | organosolv | es_ES |
dc.title | Study of a renewable capping agent addition in lignin base catalysed depolymerisation process | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2015 Elsevier under CC BY-NC-ND license | es_ES |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0016236120315209 | |
dc.identifier.doi | 10.1016/j.fuel.2020.118524 | |
dc.departamentoes | Ingeniería química y del medio ambiente | es_ES |
dc.departamentoeu | Ingeniaritza kimikoa eta ingurumenaren ingeniaritza | es_ES |