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Application of zeolites for the production of biofuels and furans from hexose sugars in ethanol

dc.contributor.authorTorres Olea, Benjamín
dc.contributor.authorPérez Merchán, Antonio Manuel
dc.contributor.authorDíaz Maizkurrena, Paula
dc.contributor.authorRequies Martínez, Jesús María ORCID
dc.contributor.authorMoreno Tost, Ramón
dc.contributor.authorCecilia, Juan Antonio
dc.contributor.authorGarcía Sancho, Cristina
dc.contributor.authorMaireles Torres, Pedro Jesús
dc.date.accessioned2024-05-02T18:00:56Z
dc.date.available2024-05-02T18:00:56Z
dc.date.issued2024-02
dc.identifier.citationCatalysis Today 427 : (2024) // Article ID 114439es_ES
dc.identifier.issn0920-5861
dc.identifier.issn1873-4308
dc.identifier.urihttp://hdl.handle.net/10810/67316
dc.description.abstractThe use of zeolites as catalysts in the transformation of glucose and 5-hydroxymethylfurfural (HMF) into 5-ethoxymethylfurfural (EMF) was evaluated. The behaviour of the catalysts could be explained by their morphology, composition, acid properties and chemical coordination of the active sites. The progress of the reaction was followed by High Performance Liquid Chromatography (HPLC) and 13C Nuclear Magnetic Resonance (NMR). Several intermediates were identified, and a reaction path is proposed. Different cosolvents were also employed in this study to enhance the selectivity towards different possible valuable compounds, and they were found to have a positive influence for the production of EMF and furfural.es_ES
dc.description.sponsorshipFunding: This research was funded by Spanish Ministry of Science and Innovation (PID2021–122736OB-C42 and PID2021–122736OB-C43), FEDER (European Union) funds (PID2021–122736OB-C42, P20–00375, UMA20-FEDERJA-088) and B. Torres-Olea thanks Ministerio de Universidades for his predoctoral contract (FPU20/02334). Moreover, authors want to thank the funding for open access charge to Universidad de Málaga / CBUA.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2021–122736OB-C42es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2021–122736OB-C43es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject5-hydroxymethylfurfurales_ES
dc.subject5-ethoxymethylfurfurales_ES
dc.subjectglucosees_ES
dc.subjectdehydrationes_ES
dc.subjectetherificationes_ES
dc.subjectzeolitees_ES
dc.titleApplication of zeolites for the production of biofuels and furans from hexose sugars in ethanoles_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder© 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by- nc-nd/4.0/).es_ES
dc.rights.holderAtribución-NoComercial-SinDerivadas 3.0 España*
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0920586123004637es_ES
dc.identifier.doi10.1016/j.cattod.2023.114439
dc.departamentoesIngeniería química y del medio ambientees_ES
dc.departamentoeuIngeniaritza kimikoa eta ingurumenaren ingeniaritzaes_ES


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© 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by- nc-nd/4.0/).
Except where otherwise noted, this item's license is described as © 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by- nc-nd/4.0/).