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Iron-Catalyzed Direct α-Arylation of Ethers with Azoles

dc.contributor.authorCorrea Navarro, Arkaitz ORCID
dc.contributor.authorFiser, Béla
dc.contributor.authorGómez Bengoa, Enrique
dc.date.accessioned2018-01-16T15:48:53Z
dc.date.available2018-01-16T15:48:53Z
dc.date.issued2015-07-14
dc.identifier.citationChemical Communications (51) : 13365-13368 (2015)es_ES
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/10810/24567
dc.description.abstractThe direct α-arylation of cyclic and acyclic ethers with azoles has been achieved, which features a novel iron-catalyzed cross-dehydrogenative coupling (CDC) process. This practical oxidative method allowed the efficient C2-alkylation of a variety of (benzo)azoles constituting straightforward access to heterocycles of utmost medicinal significance and highlighting the convenient use of feedstock substrates and iron catalysts. A preliminary mechanism supported by DFT calculations is discussed as well.es_ES
dc.description.sponsorshipMINECO for a Ramón y Cajal research contract (RYC-2012-09873) FP7 Marie Curie Actions of the European Commission via the ITN ECHONET network (MCITN-2012-316379).es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/RYC-2012-09873es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/2012-316379es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.subjectarylationes_ES
dc.subjectiron catalysises_ES
dc.subjectetherses_ES
dc.subjectazoleses_ES
dc.titleIron-Catalyzed Direct α-Arylation of Ethers with Azoleses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderAtribución-NoComercial 3.0 España
dc.relation.publisherversionhttp://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc05005ges_ES
dc.identifier.doi10.1039/c5cc05005g
dc.contributor.funderEuropean Commission
dc.departamentoesQuímica orgánica Ies_ES
dc.departamentoeuKimika organikoa Ies_ES


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Except where otherwise noted, this item's license is described as Atribución-NoComercial 3.0 España