dc.contributor.author | Pérez Camargo, Ricardo Arpad | |
dc.contributor.author | Liu, Guoming | |
dc.contributor.author | Wang, Dujin | |
dc.contributor.author | Müller Sánchez, Alejandro Jesús ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.date.accessioned | 2023-02-22T15:50:42Z | |
dc.date.available | 2023-02-22T15:50:42Z | |
dc.date.issued | 2022-05-05 | |
dc.identifier.citation | Chinese Journal of Polymer Science 40(6) : 658-691 (2022) | es_ES |
dc.identifier.issn | 1439-6203 | |
dc.identifier.issn | 0256-7679 | |
dc.identifier.uri | http://hdl.handle.net/10810/60038 | |
dc.description.abstract | The crystallization kinetics of semicrystalline polymers is often studied with isothermal experiments and analyzed by fitting the data with analytical expressions of the Avrami and Lauritzen and Hoffman (LH) theories. To correctly carry out the analysis, precautions both in experiments and data fitting should be taken. Here, we systematically discussed the factors that influence the validity of the crystallization kinetics study. The basic concepts and fundamentals of the Avrami and LH theories were introduced at first. Then, experimental protocols were discussed in detail. To clarify the impact of various experimental parameters selected common polymers, i.e., polypropylene and polylactide, were studied using various experimental techniques (i.e., differential scanning calorimetry and polarized light optical microscopy). Common mistakes were simulated under conditions when non-ideal experimental parameters were applied. Furthermore, from a practical point of view, we show how to fit the experimental data to the Avrami and the LH theories, using an Origin ® App developed by us. | es_ES |
dc.description.sponsorship | This work was financially supported by the the National Natural Science Foundation of China (Nos. 21922308 and 51820105005) and the National Key R&D Program of China (No. 2017YFE0117800). We would also like to acknowledge the financial support from the BIODEST project; this project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 778092. The funding of MICINN (Spain) through grant PID2020-113045GB-C21 is gratefully acknowledged. G. L. is grateful to the Youth Innovation Promotion Association of the Chinese Academy of Sciences (No. Y201908) | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Springer Nature | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/778092 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2020-113045GB-C21 | es_ES |
dc.rights | info:eu-repo/semantics/embargoedAccess | es_ES |
dc.subject | isothermal crystallization | es_ES |
dc.subject | avrami equation | es_ES |
dc.subject | Lauritzen and Hoffman theory | es_ES |
dc.subject | thermal analysis | es_ES |
dc.subject | step-crystallization | es_ES |
dc.title | Experimental and Data Fitting Guidelines for the Determination of Polymer Crystallization Kinetics | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2022, Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences | es_ES |
dc.relation.publisherversion | https://link.springer.com/article/10.1007/s10118-022-2724-2 | es_ES |
dc.identifier.doi | 10.1007/s10118-022-2724-2 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Ciencia y tecnología de polímeros | es_ES |
dc.departamentoeu | Polimeroen zientzia eta teknologia | es_ES |