dc.contributor.author | Wang, Zefan | |
dc.contributor.author | Dong, Xia | |
dc.contributor.author | Cavallo, Dario | |
dc.contributor.author | Wang, Dujin | |
dc.contributor.author | Müller Sánchez, Alejandro Jesús | |
dc.date.accessioned | 2023-02-22T16:17:23Z | |
dc.date.available | 2023-02-22T16:17:23Z | |
dc.date.issued | 2021-07-31 | |
dc.identifier.citation | Polymer Crystallization 4(5) : (2021) // Article ID e10201 | es_ES |
dc.identifier.issn | 2573-7619 | |
dc.identifier.uri | http://hdl.handle.net/10810/60039 | |
dc.description | Unformatted post-print version of the accepted article | es_ES |
dc.description.abstract | The self-nucleation behavior of a polybutene-1/ethylene random copolymer, P(B1-ran-E), which undergoes a complex crystal-crystal transition behavior, has been studied in detail. Similar to PE random copolymers, this material shows a strong melt memory effect even above equilibrium melting point of PB-1 homopolymer. Different polymorphic forms can be obtained when P(B1-ran-E) is cooled from different self-nucleation Domains. The trigonal form I' could only be nucleated in the presence of remaining form I crystals via self-seeding, while the melt memory in Domain IIa could only act as self-nuclei for kinetically favored form II. Furthermore, observations from optical microscopy illustrated that melt memory is able to enhance nucleation density but it does not affect the spherulitic growth rate. | es_ES |
dc.description.sponsorship | Financial supports from the National Science Foundation of China (Grant No. U1510207) and the Key Program for Coal-based Science and Technology of Shanxi Province (MH-2014-08) are gratefully acknowledged. We would like to acknowledge the financial support from the BIODEST project, this project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 778092. AJM would also like to acknowledge funding from the Basque Government through grant IT1309-19. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/778092 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.subject | polybutene-1 | es_ES |
dc.subject | self-nucleation | es_ES |
dc.subject | melt memory | es_ES |
dc.title | Peculiar self-nucleation behavior of a polybutene-1/ethylene random copolymer | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2021 Wiley Periodicals LLC. | es_ES |
dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/10.1002/pcr2.10201 | es_ES |
dc.identifier.doi | 10.1002/pcr2.10201 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Ciencia y tecnología de polímeros | es_ES |
dc.departamentoeu | Polimeroen zientzia eta teknologia | es_ES |